Nonaqueous electrolytic solution and lithium secondary battery employing the same
View Patent ↗1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I): in which R represents a substituting group such as an alkylcarbonyl group, an alkoxycarbonyl group, an aryloxy-carbonyl group, and an alkanesulfonyl group, under the condition that at least one hydrogen atom contained in the substituting group can be substituted with a halogen atom or an aryl group.
1. A non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, which further contains a pentafluorophenoxy compound having the formula (I):
in which R represents a substituting group selected from the group consisting of an alkylcarbonyl group having 2-12 carbon atoms, an alkoxycarbonyl group having 2-12 carbon atoms, an aryloxycarbonyl group having 7-18 carbon atoms, and an alkanesulfonyl group having 1-12 carbon atoms, provided that at least one hydrogen atom contained in the substituting group can be replaced with a halogen atom or an aryl group having 6-18 carbon atoms.
2. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is contained in the electrolytic solution in an amount of 0.01 to 20 wt. %.
3. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is contained in the electrolytic solution in an amount of 0.05 to 10 wt. %.
4. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is contained in the electrolytic solution in an amount of 0.1 to 5 wt. %.
5. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is at least one compound selected from the group consisting of pentafluorophenyl acetate, pentafluorophenyl propionate, pentafluorophenyl butyrate, pentafluorophenyl trifluoroacetate, pentafluorophenyl pentafluoropropionate, pentafluorophenyl acrylate, and pentafluorophenyl methacrylate.
6. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is at least one compound selected from the group consisting of methyl pentafluorophenylcarbonate, ethyl pentafluorophenylcarbonate, tert-butyl pentafluorophenylcarbonate, 9-fluorenylmethyl pentafluorophenylcarbonate, and 2,2,2-trifluoroethyl pentafluorophenylcarbonate.
7. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is at least one compound selected from the group consisting of phenyl pentafluorophenylcarbonate and dipentafluorophenyl carbonate.
8. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is at least one compound selected from the group consisting of pentafluorophenyl methanesulfonate, pentafluorophenyl ethanesulfonate, pentafluorophenyl propanesulfonate, pentafluorophenyl trifluoromethanesulfoanate, and pentafluorophenyl 2,2,2-trifluoroethanesulfonate.
9. The non-aqueous electrolytic solution defined in claim 1 , in which the pentafluorophenoxy compound is at least one compound selected from the group consisting of pentafluorophenyl methanesulfonate, pentafluorophenyl acetate, and methyl pentafluorophenylcarbonate.
10. The non-aqueous electrolytic solution defined in claim 1 , in which the non-aqueous solvent is a mixture of a cyclic carbonate and a linear carbonate.
11. The non-aqueous electrolytic solution defined in claim 10 , in which a volume ratio between the cyclic carbonate and the linear carbonate is in the range of 5:95 to 45:55.
12. The non-aqueous electrolytic solution defined in claim 1 , in which the electrolytic salt is at least one salt selected from the group consisting of LiPF 6 , LiBF 4 , LiClO 4 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiC(SO 2 CF 3 ) 3 , LiPF 4 (CF 3 ) 2 , LiPF 3 (C 2 F 5 ) 3 , LiPF 3 (CF 3 ) 3 , LiPF 3 (iso-C 3 F 7 ) 3 , and LiPF 5 (iso-C 3 F 7 ).
13. A lithium secondary battery which comprises a positive electrode, a negative electrode, and a non-aqueous electrolytic solution comprising an electrolytic salt in a non-aqueous solvent, in which the non-aqueous electrolytic solution further contains a pentafluorophenoxy compound having the formula (I):
in which R represents a substituting group selected from the group consisting of an alkylcarbonyl group having 2-12 carbon atoms, an alkoxycarbonyl group having 2-12 carbon atoms, an aryloxycarbonyl group having 7-18 carbon atoms, and an alkanesulfonyl group having 1-12 carbon atoms, provided that at least one hydrogen atom contained in the substituting group can be replaced with a halogen atom or an aryl group having 6-18 carbon atoms.
14. The lithium secondary battery of claim 13 , in which the pentafluorophenoxy compound is contained in the electrolytic solution in an amount of 0.01 to 20 wt. %.
15. The lithium secondary battery of claim 13 , in which the pentafluorophenoxy compound is contained in the electrolytic solution in an amount of 0.1 to 5 wt. %.
16. The lithium secondary battery of claim 13 , in which the positive electrode comprises at least one active material selected from the group consisting of LiCoO 2 , LiMn 2 O 4 , LiNiO 2 , and LiCo 1-x Ni x O 2 under the condition of 0.01<x<1.
17. The lithium secondary battery of claim 13 , in which the negative electrode comprises artificial graphite or natural graphite as active material.