Novel cationic polymers containing amidinium groups and their use
Cationic polymers comprising cyclic nonaromatic units which contain an amidinium group, with the cyclic nonaromatic units which contain an amidinium group being located (i) in the main chain of the polymer or (ii) in the side chains of the polymer, where in this case the polymer is neither a vinyl polymer, a polyglycoside or a polyorganosiloxane, or (iii) both in the main chain and in the side chains, and their preparation and use are described.
1 . A cationic polymer comprising cyclic nonaromatic units which comprise an amidinium group, with the cyclic nonaromatic units which comprise an amidinium group located in the main chain of the polymer, wherein the cyclic nonaromatic units which comprise an amidinium group are linked to the main chain of the polymer via the two N atoms.
2 . The cationic polymer as claimed in claim 1 , wherein the cyclic nonaromatic units which comprise an amidinium group are substituted or unsubstituted 5-, 6- or 7-membered rings or combinations thereof.
3 . The cationic polymer as claimed in claim 2 , wherein the cyclic nonaromatic units which comprise an amidinium group are selected from the group consisting of substituted and unsubstituted imidazolinium, tetrahydropyrimidinium tetrahydro-1,3-diazepinium groups and combinations thereof.
4 . The cationic polymer as claimed in claim 1 which comprises the following structural unit in the main chain:
wherein R 1 is —(CH 2 ) n — where n=2, 3 or 4;
R 2 is —(CH 2 ) m — where 0<m<22,
—CH═CH—CH 2 —,
—CH═CH—CH 2 —CH 2 —,
—CH═CH—,
—CH═CH—CH=CH—,
a monocyclic or polycyclic arylene radical or
a divalent polyether radical of the structure —(CH 2 ) k —(O—(CH 2 ) k ) p — where 0<k<22 and 0<p<100, ; and
R 3 is —(CH 2 ) 1 —CH 3 where 0<1<21 or a monocyclic or polycyclic aryl radical.
5 . The cationic polymer as claimed in claim 4 , wherein n=2 and R 2 ═R 1 and the cationic polymer is prepared from essentially linear polyethylenamine.
6 . The cationic polymer as claimed in claim 1 comprising at least one counterion selected from the group consisting of iodide, halide, phosphate, halophosphates, alkyl phosphates, nitrate, sulfate, hydrogensulfate, alkyl sulfates, aryl sulfates, perfluorinated alkyl and aryl sulfates, sulfonate, alkylsulfonates, arylsulfonates, perfluorinated alkylsulfonates and arylsulfonates, perchlorate, tetrachloroaluminate, tetrafluoroborate, alkyl borates, tosylate, saccharinate, alkyl carboxylates, bis(perfluoroalkylsulfonyl)amide anions and mixtures thereof.
7 . The cationic polymer as claimed in claim 6 wherein the counterion is iodide.
8 . The cationic polymer as claimed in claim 1 which comprises at least one counterion capable of producing liquid-crystalline states.
9 . A process for preparing the cationic polymer as claimed in claim 4 comprising reacting a predominantly linear polyethylenamine with an ortho ester in the presence of an ammonium salt which comprises weakly nucleophilic anion wherein R 1 ═R 2 ═—CH 2 —CH 2 —.
10 . A polyelectrolyte comprising the cationic polymer as claimed in claim 1 , wherein the polvelectrolyte is comprised in a battery or a solar cell.
11 . An additive for polymers comprising the cationic polymer as claimed in claim 1 .
12 . An optical component comprising the cationic polymer as claimed in claim 1.