Organic polymer having epoxy-and/or oxetanyl-containing silicon group at the end and process for producing the same
View Patent ↗An organic polymer is provided which has an end structure expressed by general formula (1): In the formula, R 1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—. R 2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—. X represents a monovalent organic group having an epoxy group and/or an oxetanyl group. m represents an integer in the range of 0 to 20. n represents an integer of 1, 2, or 3.
1. An organic polymer having an end structure expressed by general formula (1):
(wherein R 1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; R 2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; if the number of R 1 s or R 2 s is at least two, they may be the same or different; R′ represents a monovalent hydrocarbon group having a carbon number in the range of 1 to 20 and the three R′s may be the same or different; X represents a monovalent organic group having an epoxy group and/or an oxetanyl group, and if the number of Xs is at least two, they may be the same or different; m represents an integer in the range of 0 to 20; and n represents an integer of 1, 2, or 3), and
wherein the main chain skeleton of the organic polymer comprises a saturated hydrocarbon polymer selected from the group consisting of polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and copolymers thereof.
2. An organic polymer having an end structure expressed by general formula (2):
(wherein R 1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; R 2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; if the number of R 1 s or R 2 s is at least two, they may be the same or different; R′ represents a monovalent hydrocarbon group having a carbon number in the range of 1 to 20 and the three R′s may be the same or different; R 3 represents a divalent organic group having a carbon number in the range of 1 to 20 and containing at least one constituent atom selected from the group consisting of hydrogen, oxygen, and nitrogen; and m represents an integer in the range of 0 to 20), and
wherein the main chain skeleton of the organic polymer comprises a saturated hydrocarbon polymer selected from the group consisting of polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and copolymers thereof.
3. An organic polymer having an end structure expressed by general formula (3):
(wherein R 1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; R 2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; if the number of R 1 s or R 2 s is at least two, they may be the same or different; R′ represents a monovalent hydrocarbon group having a carbon number in the range of 1 to 20 and the three R′s may be the same or different; R 4 represents a divalent organic group having a carbon number in the range of 1 to 20 and containing at least one constituent atom selected from the group consisting of hydrogen, oxygen, and nitrogen; and m represents an integer in the range of 0 to 20), and
wherein the main chain skeleton of the organic polymer comprises a saturated hydrocarbon polymer selected from the group consisting of polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and copolymers thereof.
4. An organic polymer having an end structure expressed by general formula (4):
(wherein R 1 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; R 2 represents an alkyl group having a carbon number in the range of 1 to 20, an aryl group having a carbon number in the range of 6 to 20, an aralkyl group having a carbon number in the range of 7 to 20, an alkoxy group having a carbon number in the range of 1 to 20, or a triorganosiloxy group expressed by (R′) 3 SiO—; if the number of R 1 s or R 2 s is at least two, they may be the same or different; R′ represents a monovalent hydrocarbon group having a carbon number in the range of 1 to 20 and the three R′s may be the same or different; R 5 represents a divalent organic group having a carbon number in the range of 1 to 20 and containing at least one constituent atom selected from the group consisting of hydrogen, oxygen, and nitrogen; and m represents an integer in the range of 0 to 20), and
wherein the main chain skeleton of the organic polymer comprises a saturated hydrocarbon polymer selected from the group consisting of polyisobutylene, hydrogenated polyisoprene, hydrogenated polybutadiene, and copolymers thereof.
5. The organic polymer according to claim 1 , wherein at least one X has a structure expressed by the following formula:
6. The organic polymer according to claim 1 , wherein at least one X has a structure expressed by the following formula:
7. The organic polymer according to claim 1 , wherein the organic polymer is produced by an addition reaction of an organic polymer having an unsaturated group at an end thereof with a hydrosilane compound having an epoxy group and/or an oxetanyl group.
8. A process for producing the organic polymer as set forth in claim 1 , the process comprising the step of performing an addition reaction of an organic polymer having an unsaturated group at an end thereof with a hydrosilane compound having an epoxy group and/or an oxetanyl group.
9. The organic polymer according to claim 1 , wherein the organic polymer is produced by an exchange reaction of a hydrolyzable group between an organic polymer having a hydrolyzable silyl group at an end thereof and a compound having at least one epoxy and/or oxetanyl group and one hydroxyl group in one molecule thereof.
10. A process for producing the organic polymer as set forth in claim 1 , the process comprising the step of performing an exchange reaction of a hydrolyzable group between an organic polymer having a hydrolyzable silyl group at an end thereof and a compound having at least one epoxy and/or oxetanyl group and one hydroxyl group in one molecule thereof.