Blockcopolymer compositions, having improved mechanical properties and processability and styrenic blockcopolymer to be used in them
View Patent ↗A composition to be used for the manufacture of fibers, filaments, melt blown or spun bond non-wovens or cast or blown films, comprising at least 50 wt % of a styrenic block copolymer; a polyolefin in an amount of from 10 to 30 wt %; a resin which is compatible with the poly(styrene) blocks in the styrenic block copolymer in an amount of at least 5 wt %, and a resin which is compatible with the hydrogenated polybutadiene blocks in the styrenic block copolymer an amount of at least 3 wt %, wherein all weight percentages are relative to the weight of the complete composition; styrenic block copolymers to be used therein; and fibers, melt blown or spun bond non-wovens or cast or blown films prepared from it.
1. A composition for the manufacture of fibers, filaments, melt blown or spun bond non-wovens or cast or blown films, comprising
(1) at least 50 wt % of a styrenic block copolymer, having a molecular structure according to the general formula
S-EB-S(1) or (S-EB) n X(2),
wherein each S independently is a polymer block of predominantly styrene and EB is a hydrogenated polymer block of predominantly butadiene, n is an integer equal to or greater than 2, and X is the residue of a coupling agent, having a poly(styrene) content in the range of from 10 to 29 wt %, having poly(styrene) blocks (S) of an apparent molecular weight in the range of from 6,000 to 9,000, having an apparent molecular weight of the complete block copolymer in the range of from 80,000 to 150,000, having an 1,2-addition degree (vinyl content) in the precursor of the poly (butadiene) block (EB) in the range of from 60 to 80% (mole/mole), wherein the block EB has a hydrogenation degree of at least 80%, and wherein diblock S-EB optionally occurs in a content of at most 20 mole %;
(2) a polyolefin in an amount of from 10 to 30 wt %;
(3) a resin which is compatible with the poly(styrene) blocks selected from coumarone-indene resin, polyindene resin, poly(methyl indene) resin, polystyrene resin, vinyltoluene-alphamethylstyrene resin, alphamethylstyrene resin, and polyphenylene ether in an amount of at least 5 wt %, and
(4) a resin which is compatible with the hydrogenated polybutadiene blocks selected from compatible C 5 hydrocarbon resins, hydrogenated C 5 hydrocarbon resins, styrenated C 5 resins, C 5/ C 9 resins, styrenated terpene resins, fully hydrogenated or partially hydrogenated C 9 hydrocarbon resins, rosins esters, rosins derivatives and mixtures thereof in an amount of at least 3 wt %,
wherein all weight percentages are relative to the weight of the complete composition.
2. The composition of claim 1 , wherein the poly(styrene) content is in the range of from 17 to 24 wt %.
3. The composition of claim 2 , wherein the poly(styrene) blocks (S) have an apparent molecular weight in the range of from 7,000 to 8,500.
4. The composition of claim 1 , wherein the polyolefin is a polypropylene having a melt flow rate greater than 400 gr/10 min (according to ASTM D1238-95).
5. The composition of claim 1 , wherein the block EB of the block copolymer has a hydrogenation degree of at least 90%.
6. The composition of claim 4 , wherein the block EB of the block copolymer has a hydrogenation degree of at least 95%.
7. The composition of claim 3 , wherein the EB block precursor has an 1,2-addition degree (vinyl content) in the range of from 65 to 75%.
8. The composition of claim 6 , wherein the EB block precursor has an 1,2-addition degree (vinyl content) in the range of from 65 to 75%.
9. The composition of claim 1 , wherein any S-EB diblock occurs in a content of at most 10 mole %, relative to the total block copolymer amount.
10. The composition of claim 8 , wherein any S-EB diblock occurs in a content of at most 10 mole %, relative to the total block copolymer amount.
11. The composition of claim 2 wherein the poly(styrene) blocks (S) have an apparent molecular weight in the range of from 6,000 to 7,000.
12. The composition of claim 11 wherein the apparent molecular weight of the complete block copolymer is in the range of from 100,000 to 150,000.
13. The composition of claim 12 wherein the 1,2-addition degree (vinyl content) in the precursor of the poly(butadiene) block (EB) is in the range of from 65 to 80% (mole/mole).
14. The composition of claim 12 wherein the 1,2-addition degree (vinyl content) in the precursor of the poly(butadiene) block (EB) is in the range of from 75 to 80% (mole/mole).
15. The composition of claim 14 wherein the block EB has a hydrogenation degree of at least 90%.
16. The composition of claim 15 wherein the polyolefin is a polypropylene having a melt flow rate greater than 400 gr/10 min (according to ASTM D1238-95).
17. Fibers, filaments, melt blown or spun bond non-wovens or cast or blown films, derived from a composition comprising
(1) at least 50 wt % of a styrenic block copolymer, having a molecular structure according to the general formula
S-EB-S(1) or (S-EB) n X(2),
wherein each S independently is a polymer block of predominantly styrene and EB is a hydrogenated polymer block of predominantly butadiene, n is an integer equal to or greater than 2, and X is the residue of a coupling agent, having a poly(styrene) content in the range of from 10 to 29 wt %, having poly(styrene) blocks (S) of an apparent molecular weight in the range of from 6,000 to 9,000, having an apparent molecular weight of the complete block copolymer in the range of from 80,000 to 150,000, having an 1,2-addition degree (vinyl content) in the precursor of the poly (butadiene) block (EB) in the range of from 60 to 80% (mole/mole), wherein the block EB has a hydrogenation degree of at least 80%, and wherein diblock S-EB optionally occurs in a content of at most 20 mole %;
(2) a polyolefin in an amount of from 10 to 30 wt %;
(3) a resin which is compatible with the poly(styrene) blocks selected from coumarone-indene resin, polyindene resin, poly(methyl indene) resin, polystyrene resin, vinyltoluene-alphamethylstyrene resin, alphamethylstyrene resin, and polyphenylene ether in an amount of at least 5 wt %, and
(4) a resin which is compatible with the hydrogenated polybutadiene blocks selected from compatible C 5 hydrocarbon resins, hydrogenated C 5 hydrocarbon resins, styrenated C 5 resins, C 5/ C 9 resins, styrenated terpene resins, fully hydrogenated or partially hydrogenated C 9 hydrocarbon resins, rosins esters, rosins derivatives and mixtures thereof in an amount of at least 3 wt %,
wherein all weight percentages are relative to the weight of the complete composition; processing aids; and stabilizing ingredients.
18. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 17 wherein the poly(styrene) blocks (S) have an apparent molecular weight in the range of from 6,000 to 7,000.
19. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 18 wherein the apparent molecular weight of the complete block copolymer is in the range of from 100,000 to 150,000.
20. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 19 wherein the 1,2-addition degree (vinyl content) in the precursor of the poly(butadiene) block (EB) is in the range of from 65 to 80% (mole/mole).
21. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 19 wherein the 1,2-addition degree (vinyl content) in the precursor of the poly(butadiene) block (EB) is in the range of from 75 to 80% (mole/mole).
22. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 21 wherein the block EB has a hydrogenation degree of at least 90%.
23. The fibers, filaments, melt blow or spun bond non-wovens or cast or blown films of claim 22 wherein the polyolefin is a polypropylene having a melt flow rate greater than 400 gr/10 min (according to ASTM D1238-95).
24. The composition of claim 17 , wherein the poly(styrene) content is in the range of from 17 to 24 wt %.
25. The composition of claim 24 , wherein the poly(styrene) blocks (S) have an apparent molecular weight in the range of from 7,000 to 8,500.
26. The composition of claim 17 wherein the polyolefin is a polypropylene having a melt flow rate greater than 400 gr/10 min (according to ASTM D1238-95).
27. The composition of claim 17 , wherein the block EB of the block copolymer has a hydrogenation degree of at least 90%.
28. The composition of claim 26 , wherein the block EB of the block copolymer has a hydrogenation degree of at least 95%.
29. The composition of claim 25 , wherein the EB block precursor has an 1,2-addition degree (vinyl content) in the range of from 65 to 75%.
30. The composition of claim 28 , wherein the EB block precursor has an 1,2-addition degree (vinyl content) in the range of from 65 to 75%.
31. The composition of claim 17 , wherein any S-EB diblock occurs in a content of at most 10 mole %, relative to the total block copolymer amount.
32. The composition of claim 30 , wherein any S-EB diblock occurs in a content of at most 10 mole %, relative to the total block copolymer amount.