Syntactic polyolefin composition for pipe coating
View Patent ↗The invention relates to a syntactic polyolefin composition for pipe coating, wherein the composition comprises a β-nucleated propylene polymer and microspheres. The invention also relates to a method for the preparation of the composition for pipe coating and to an off-shore pipe coated with the syntactic polyolefin composition.
1. A syntactic polyolefin composition for pipe coating, wherein the composition comprises:
a β-nucleated propylene polymer comprising 0.0001–2.0 weight % of a β-nucleating agent,
a polyolefin homopolymer having a melt flow rate of 100–1500 g/10 min at 230° C./2.16 kg, and
microspheres,
said composition having a melt flow rate (MFR 2 ; ISO 1133, condition D) at 230° C./2.16 kg in the range of 0.05–30 g/10 min and an elongation at break of at least 3%.
2. A syntactic polyolefin composition according to claim 1 , wherein said composition has a melt flow rate (MFR 2 ; ISO 1133, condition D) at 230° C./2.16 kg in the range of 0.5–10 g/10 min.
3. A syntactic polyolefin composition according to claim 1 , wherein said composition has an elongation at break of >5%.
4. A syntactic polyolefin composition according to claim 1 , wherein the β-nucleated propylene polymer is a (co)polymer which comprises at least 90.0 weight % of propylene and up to 10.0 weight % of α-olefins with 2 or 4 to 18 carbon atoms, and that the propylene polymer has a melt flow rate of 0.1–8 g/10 min at 230° C./2.16 kg.
5. A syntactic polyolefin composition according to claim 1 , wherein the amount of polyolefin is 0–20 weight %.
6. A syntactic polyolefin composition according to claim 1 , wherein the tensile modulus of the composition is at least 1500 MPa determined according to ISO 527.
7. A syntactic polyolefin composition according to claim 1 , wherein the compression strength at 20 MPa/80° determined according to ASTM D695, is >10 MPa.
8. A syntactic polyolefin composition according to claim 1 , wherein the K-value of the composition is less than 0.190 W/m° K.
9. A syntactic polyolefin composition according claim 1 , wherein the density of the composition is 500–850 kg/m3.
10. A syntactic polyolefin composition according to claim 1 , wherein said microspheres are made of glass, ceramics, epoxy resin, phenolic resin or urea-formaldehyde resin.
11. A syntactic polyolefin composition according to claim 1 , wherein said microspheres are untreated microspheres.
12. A syntactic polyolefin composition according to claim 1 , wherein said microspheres have an outer diameter of 1–500 μm.
13. A syntactic polyolefin composition according to claim 1 , wherein said microspheres are hollow.
14. A syntactic polyolefin composition according to claim 1 , wherein said microspheres are present in an amount of 10–50 weight % of the composition.
15. A method for the preparation of a syntactic polyolefin composition for pipe coating according to claim 1 , wherein the microspheres are evenly distributed by melt mixing in a composition comprising a β-nucleated propylene polymer and microspheres, said composition having a melt flow rate at 230° C./2.16 kg in the range 0.05–30 g/10 min and in that the composition has an elongation at break of at least 3%.
16. A method according to claim 15 , wherein said microspheres are added to the molten polymer.
17. A method according to claim 15 , wherein the composition is compounded/homogenised and extruded as a coating on an off-shore pipe in one continuous step.
18. A method according to claim 15 , wherein the composition is pelletized in a first step and in a subsequent step extruded as a coating on an off-shore pipe.
19. An off-shore pipe coated with a syntactic polyolefin composition, wherein the pipe is coated with a composition according to claim 1 .
20. A syntactic polyolefin composition according to claim 1 , wherein said composition has a melt flow rate (MFR 2 ; ISO 1133, condition D) at 230° C./2.16 kg in the range of 1.0–5 g/10 min.
21. A syntactic polyolefin composition according to claim 1 , wherein said composition has an elongation at break of >10%.
22. A syntactic polyolefin composition according to claim 1 , wherein the amount of polyolefin is 15–20 weight %.
23. A syntactic polyolefin composition according to claim 1 , wherein the compression strength at 20 MPa/80° determined according to ASTM D695, is >15 MPa.
24. A syntactic polyolefin composition according to claim 1 , wherein said microspheres have an outer diameter of 5–200 μm.
25. A syntactic polyolefin composition according to claim 1 , wherein said microspheres are present in an amount of 20–30 weight % of the composition.