Rotomoulding polyethylene and method for producing said rotomoulding polyethylene
View Patent ↗A method for producing rotomoulding polyethylene by fluidized bed gas phase polymerisation of ethylene and the improved rotomoulding polyethylene obtainable by the process.
1. A process for producing polyethylene for rotomoulding, having a density A of from 930 to 944 kg/m 3 and a melt index B of from 3 to 7.8 g/10 min, by (co-)polymerization of ethylene in a fluidised bed gas phase reactor, said process comprising
determining the instantaneous density d and melt index MI of the polyethylene powder exiting a fluidized bed gas phase reactor,
allowing the density and melt index to vary around their A and B values by a value of plus or minus 3 kg/m 3 for the density and plus or minus 30% for the melt index,
wherein the operating temperature is controlled such that
a.) an RTSE factor is first maintained in an operating envelope corresponding to the d and MI values of the polyethylene produced, and
b.) then the RTSE factor is maintained between 4.2 and 4.4.
2. The process according to claim 1 , wherein the density and melt index are respectively allowed to vary around their A and B values by a value of plus or minus 2 kg/m 3 for the density and plus or minus 15% for the melt index.
3. The process according to claim 1 or 2 , wherein the RTSE factor is allowed to vary only by plus or minus 0.07 across the operating envelope(s), said variation occurring within a minimum of 4 hours of operation.
4. The process according to claim 3 , wherein the RTSE variation is only allowed within a minimum of 8 hours of operation.
5. The process according to claims 3 , wherein the RTSE factor is allowed to vary only by plus or minus 0.05 across the operating envelope(s).
6. The process according to claim 1 , wherein the process is applied during product grade transition between two polyethyenes for rotomoulding.
7. The process according claim 1 , wherein the polyethylene is a copolymer of ethylene and hex-1-ene.
8. The process according to claim 1 , wherein the polyethylene for rotomoulding has a density of from 933 to 941 kg/m 3 and a melt index of from 3 to 7 g/10 min.
9. A polyethylene for rotomoulding produces by the process of claim 1 , and having a density of from 930 to 944 kg/m 3 , a melt index according to ASTM-D-1238, condition A (2.16 kg) of from 3 to 7.8 g/10 min, an ESCR property according to ASTM-D-1693 equal or higher than 400 h and a Charpy property equal or higher than 10 kJ/m 2 .
10. A hex-1-ene copolymer of ethylene having a density of from 930 to 944 kg/m 3 and a melt index according to ASTM-D-1238, condition A (2.16 kg) of from 3 to 7.8 g/10 min, an ESCR property according to ASTM-D-1693 equal or higher than 400 h and a Charpy property equal or higher than 10 kJ/m 2 .