Fuel reformer and method for producing the same, electrode for use in electrochemical device, and electrochemical device
View Patent ↗A fuel reformer which can easily achieve high weight energy density and high volume energy density, and a method for producing the fuel reformer with ease and high efficiency as well as an electrode for electrochemical device, such as a fuel cell, and an electrochemical device are provided. The present invention is to feed hydrogen obtained from a fuel reformer having a catalyst layer containing Pt for taking out hydrogen from a liquid fuel, such as methanol, and a hydrogen permeable layer, such as a Pd thin film, which is impermeable to liquid and permeable to hydrogen to an electrochemical device such as a fuel cell, which comprises a negative electrode, a positive electrode and a proton conductive film sandwiched therebetween. The present invention provides a method of producing the hydrogen permeable layer in the reformer by forming the hydrogen permeable layer and the catalyst layer on a base layer comprising Al or the like, and removing the base layer by dissolution.
1. A method for producing a fuel reformer, comprising:
preparing a fuel reforming portion by:
forming a base layer on a planar substrate;
forming a hydrogen permeable layer on the base layer;
forming a reforming catalyst layer on the hydrogen permeable layer, wherein the reforming catalyst layer is formed with a catalyst bound by a binder; and
removing the entire base layer to cause the entire substrate to separate from the hydrogen permeable layer and the reforming catalyst layer and to obtain a two layer integrated article consisting of the hydrogen permeable layer and the reforming catalyst layer, and
forming a catalyst electrode on a side of the hydrogen permeable layer, the catalyst electrode having a catalyst layer comprising a noble metal carried carbon and an ionic conductive binder.
2. The method for producing a fuel reformer of claim 1 , in which, the base layer is removed by dissolution in any one of an acid, an alkali, and an organic solvent.
3. The method for producing a fuel reformer of claim 1 , in which the base layer is formed with aluminum or alloy thereof.
4. The method for producing a fuel reformer of claim 1 , in which the hydrogen permeable layer is formed to have a thickness of about 2 μm or less.
5. The method for producing a fuel reformer of claim 1 , in which a film selected from the group consisting of platinum, palladium, gold, iridium, silver, rhodium, ruthenium and combinations thereof is formed as the hydrogen permeable layer.
6. The method for producing a fuel reformer of claim 1 , in which a catalyst layer containing an element of the platinum group is formed as the catalyst layer.
7. The method for producing a fuel reformer of claim 6 , in which a catalyst layer comprising a noble metal carried on ceramic is formed as the catalyst layer.
8. The method for producing a fuel reformer of claim 6 , in which a catalyst layer comprising a noble metal carried on carbon powder is formed as the catalyst layer.
9. The method for producing a fuel reformer of claim 1 , in which the binder is selected from the group consisting of an ionic conductive organic binder and an organic binder, each containing fluorine, wherein the ionic conductive organic binder optionally includes perfluorosulfonic acid, and wherein the organic binder optionally includes polyvinylidenefluoride.
10. The method for producing a fuel reformer of claim 1 , in which a carbon porous layer is provided between the fuel reforming portion and the catalyst electrode.