Method for producing polyvinylacetals
View Patent ↗Polyvinyl acetals are obtained in a cost-effective and environmentally advantageous manner by employing as at least a portion of the aqueous acetalization medium, the mother liquor from a previous acetalization reaction.
1. A process for preparing polyvinyl acetals by hydrolysis of a vinyl ester polymer and acetalization of the resultant polyvinyl alcohol with one or more aldehydes selected from the group consisting of aliphatic and aromatic aldehydes having 1 to 15 carbon atoms, comprising:
a) providing a polyvinyl alcohol to form an initial charge in an aqueous medium,
b) if necessary, adding acid to adjust to a pH of <1,
c) initiating acetalization by addition of an aldehyde component, and
d) precipitating polyvinyl acetal and separating polyvinyl acetal via filtration from a filtrate,
wherein from 10 to 100% by weight of the aqueous medium of a) comprises the filtrate from a preceding batch of polyvinyl acetal production, and, optionally reusing the filtrate produced in d) in a further polyvinyl acetal production batch.
2. The process of claim 1 , wherein the filtrate produced in step d) is reused in a further production of polyvinyl acetal.
3. The process of claim 1 , wherein the vinyl ester polymer contains one or more monomer units selected from the group consisting of vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methylvinyl acetate, vinyl pivalate, and vinyl esters of α-branched monocarboxylic acids having 5 to 11 carbon atoms.
4. The process of claim 2 , wherein the vinyl ester polymer contains one or more monomer units selected from the group consisting of vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methylvinyl acetate, vinyl pivalate, and vinyl esters of α-branched monocarboxylic acids having 5 to 11 carbon atoms.
5. The process of claim 1 , wherein the vinyl ester polymer used comprises polyvinyl acetate, a vinyl acetate-1-methylvinyl acetate copolymer, or a vinyl acetate (meth)acrylic acid copolymer.
6. The process of claim 2 , wherein the vinyl ester polymer used comprises polyvinyl acetate, a vinyl acetate-1-methylvinyl acetate copolymer, or a vinyl acetate (meth)acrylic acid copolymer.
7. The process of claim 1 , wherein the polyvinyl alcohol has a degree of hydrolysis of 50 to 100 mol %.
8. The process of claim 1 , wherein the aldehyde(s) comprise one or more selected from the group consisting of formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, and benzaldehyde.
9. The process of claim 1 , wherein the polyvinyl alcohol forms an initial charge in the form of an aqueous solution with a concentration of 10 to 50% by weight solids, and the solids content is altered by addition of the filtrate from a preceding polyvinylacetal acetalization.
10. The process of claim 1 , wherein polyvinyl acetals are obtained with a degree of acetalization of 45 to 80 mol % and with a degree of polymerization of at least 100.