Method and equipment to control separation of a dispersion liquid-liquid extraction
View Patent ↗The invention relates to a method for the controlled separation of a dispersion of two liquids formed in the mixing stage of liquid-liquid extraction into their own phases in the separation section of the extraction. In particular the method and equipment relate to the extraction process used in the recovery of metals. In accordance with the method the dispersion band remaining between the separated phases is dammed up using at least one revert member for said purpose located in the separation section. The equipment according to the invention comprises at least one revert member, which is in turn made up of at least two separate parts.
1. A method for the controlled separation of a dispersion formed of an aqueous solution and an organic solution into their own phases in connection with the recovery of metals in a settler present in the separation section of a liquid-liquid extraction process comprising:
a) damming up the dispersion by means of at least one revert member, comprising at least two revert plates, wherein each revert plate abuts both sidewalls of the settler, and each revert plate is perpendicular to the longitudinal axis of the settler, wherein consecutive revert plates are situated at different heights to form a revert channel between the consecutive revert plates;
b) causing the dispersion to flow locally in a vertical direction in the revert channel;
c) causing the separated upper phase to flow over the revert member and/or through only the upper portion of the revert member, and causing the separated lower phase to flow under the revert member and/or through only the bottom part of the revert member; and
d) extending the upper edge of a revert plate of the revert member into the separated upper phase, wherein the revert plate has a slotted zone comprising vertical slots along the upper edge; and causing the separated upper phase to flow partially over and through the slotted zone of the revert plate.
2. The method according to claim 1 , further comprising causing the dammed dispersion to flow under the first revert plate into the first revert channel.
3. The method according claim 2 , further comprising causing the dispersion that has flowed into the revert channel to flow over the last revert plate of the revert member.
4. The method according to claim 1 , wherein the number of revert members located in the separation section is 1-6.
5. The method according to claim 1 , wherein the number of revert plates in the at least one revert member is 2-6.
6. The method according to claim 1 , wherein the metal to be recovered is selected from the group consisting of copper, uranium, cobalt, nickel and zinc.
7. Equipment for the controlled separation of a dispersion formed of an aqueous solution and an organic solution into their own phases in connection with the recovery of metals in a settler present in the separation section of a liquid-liquid extraction process, comprising: a feed end, a rear end, two sidewalls and a bottom, further comprising at least one revert member, wherein the revert member comprises at least two revert plates, wherein each revert plate abuts both sidewalls of the settler, and each revert plate is perpendicular to the longitudinal axis of the settler, wherein consecutive revert plates are situated at different heights to form a revert channel between the consecutive revert plates, and wherein the first revert plate has a slotted zone comprising vertical slots along the upper edge, wherein said slots have a length that is 5-15% of the total height of the revert plate.
8. The equipment according to claim 7 , wherein the number of revert members is 1-6.
9. The equipment according to claim 7 , wherein the number of revert plates in the at least one revert member is 2-6.
10. The equipment according to claim 7 , wherein the upper edge of the first revert plate is located above the surface of the liquid in the settler.
11. The equipment according to claim 7 , wherein the distance from the lower edge of the first revert plate to the bottom of the settler is 12-50% of the total depth of the solution in the settler.
12. The equipment according to claim 7 , wherein the first and subsequently every other revert plate has a slotted zone comprising vertical slots along the lower edge, wherein said slots have a length that is 5-15% of total the height of the revert plate.
13. The equipment according to claim 7 , wherein the second and subsequently every other revert plate has a slotted zone comprising vertical slots along the upper edge, wherein said slots have a length that is 5-15% of the total height of the revert plate.
14. The equipment according to claim 7 , wherein the distance from the lower edge of the second revert plate to the bottom of the settler is 5-35% of the total depth of the solution in the settler.
15. The equipment according to claim 7 , wherein the upper edge of the second revert plate is located below the surface of the solution, and the distance from the surface to the upper edge of the second revert plate is 12-35% of the total depth of the solution in the settler.
16. The equipment according to claim 7 , wherein the revert plates are inclined at an angle of 50-90° from the horizontal either towards or away from the rear end of the settler.
17. The equipment according to claim 16 , wherein the revert plates are inclined towards the feed end of the settler.
18. The equipment according to claim 16 , wherein the revert plates are inclined towards the rear end of the settler.
19. The equipment according claim 7 , wherein a baffle plate is located behind a slotted zone along the upper edge of the first revert plate of the revert member, as seen in the direction of the flow in the settler, wherein the baffle plate comprises vertical strips aligned with the vertical slots of the slotted zone.
20. The equipment according to claim 7 , wherein a baffle plate is located behind a slotted zone along the upper edge of the last revert plate of the revert member as seen in the direction of the flow in the settler, wherein the baffle plate comprises vertical strips aligned with the vertical slots of the slotted zone.
21. The equipment according to claim 7 , wherein the feed end of the settler is equipped with a picket fence.
22. The equipment according to claim 7 , wherein the first revert plate is situated so that the lower edge of the second revert plate is below the lower edge of the first revert plate, and the first revert plate is situated so that the upper edge of the first revert plate is above the upper edge of the second revert plate.
23. The equipment according to claim 7 , wherein the distance from the lower edge of a third revert plate to the bottom of the settler is 0-30% larger than the distance from the lower edge of the first revert plate to the bottom of the settler and wherein the distance from the upper edge of the third revert plate to the surface of the upper phase is 10-30% smaller than the distance from the upper edge of the second revert plate to the surface of the upper phase.
24. The equipment according to claim 7 , wherein the distance from the lower edge of a fourth revert plate to the bottom of the settler is 0-30% larger than the distance from the lower edge of the second revert plate to the bottom of the settler and wherein the distance from the upper edge of the fourth revert plate to the surface of the upper phase is 10-30% larger than the distance from the upper edge of the second revert plate to the surface of the upper phase.