Core-shell particles having non-polar outer surface and methods for producing a three-dimensional object from the particles
View Patent ↗The invention relates to particles for producing a three-dimensional object by using layer-building methods (powder-based generative rapid prototyping methods), to methods for producing a three-dimensional object therefrom, and to an object that can be produced by using the particles or the methods. The aim of the invention is to improve the precision of production methods of this type by preventing the tendency of the particles used to agglomerate. To this end, a surfactant layer is applied, whereby the nonpolar groups of the surfactants are oriented toward the particle surface thus forming a hydrophobic surface having a low tendency to agglomerate.
1. A particle for producing a three-dimensional object by means of layer-building processes, comprising
a core of at least a first material,
a first coating on the core with a second material, which is polar, and
a second coating on thc first coating,
wherein the thickness of the first coating corresponds to 0.1 to 10% of the mean particle radius,
wherein the second coating is formed from surfactant, the thickness of which corresponds to a monolayer of the surfactant, and
wherein a uniformly non-polar outer surface of the particle is formed.
2. The particle as claimed in claim 1 , wherein the first coating and the second coating are soluble in water or an aqueous solution but the core is not.
3. A process for producing a three-dimensional object, including the following steps:
applying a layer of particles according to claim 1 to a target surface,
irradiating a selected part of the layer, corresponding to a cross-section of the object, with an energy beam, so that the particles are joined in the selected part,
repeating the application and irradiation steps for a plurality of layers, so that the joined parts of the adjacent layers are joined together in order to form the object.
4. A process for producing a three-dimensional object, including the following steps:
applying a layer of particles according to claim 1 to a target surface,
printing a liquid in which at least parts of the particles are soluble onto a selected part of the layer, corresponding to a cross-section of the object, so that the particles are joined in the selected part,
repeating the application and printing steps to form a plurality of layers, so that the joined parts of the adjacent layers are joined together in order to form the object.