Process for controlling polyvinylbutyral physical properties by controlling stereochemistry of same
View Patent ↗The present invention is method for controlling the stereoisomerism of PVB resin as well as a PVB resin having a meso/racemic stereoisomer ratio of from about 2.5 to about 5.0. Manipulation of the PVB stereoisomer ratio can provide an additional method of controlling the physical properties of PVB, in addition to or in lieu of changing additives or manipulating the PVB composition.
1. A process for preparing a plasticized polyvinyl butyral resin composition having a mixture of meso and racemic stereoisomers, the process comprising the steps of:
(a) mixing components (i) through (v) to obtain an aqueous reaction mixture;
(b) stirring the aqueous reaction mixture for a period of from about 15 minutes to about 180 minutes at a temperature in the range of from 80° C. to about 100° C., wherein the components of the aqueous reaction mixture are (i) water, (ii) an acidic aqueous polyvinyl alcohol solution having a dry weight polyvinyl alcohol concentration of from about 8 wt % to about 20 wt %, based on the total weight of the solution, that is maintained at a temperature of at least about 80° C., (iii) an acid compound or mixture of acid compounds present in an amount sufficient to give the aqueous reaction mixture a pH of from about 1.3 to about 2.5; (iv) a surfactant selected from the group consisting of sodium methyl cocoyl taurate and mixtures of sodium methyl cocoyl taurate with sodium dioctylsulfosuccinate or sodium lauryl sulfate; said surfactant present in an amount of from about 0.1 wt % to about 0.70 wt % based on the dry weight of the polyvinyl alcohol, and (v) butyraldehyde, wherein the ratio of (ii) to (v) is sufficient such that there is unreacted hydroxyl functionality in the polyvinyl butyral resin composition;
(c) stabilizing the aqueous reaction mixture by (i) raising the pH of the aqueous reaction mixture to a pH of at least 7 and (ii) draining the liquid from the aqueous reaction mixture to obtain the polyvinyl butyral resin composition, wherein the polyvinyl butyral resin composition has a hydroxyl number of from about 15 to about 34 and further wherein the meso to racemic ratio of the polyvinyl butyral resin composition is in the range of from about 2.5 to about 5.0;
(d) mixing the polyvinyl butyral resin composition with a plasticizer in an amount of from about 30 to about 50 pph, based on the weight of the dry polyvinyl butyral resin composition, said plasticizer selected from the group consisting of triethyleneglycol di-(2-ethyl hexanoate), dibutyl sebacate and tetraethylene glycol di(2-heptanoate); and
(e) extruding the plasticized polyvinyl butyral resin composition to form a sheet having a tensile creep of less than 2.5%.
2. The process of claim 1 , wherein the surfactant consists essentially of sodium methyl cocoyl taurate.
3. The process of claim 1 wherein the surfactant mixture comprises sodium lauryl sulfate.
4. The process of claim 1 wherein the surfactant mixture comprises sodium dioctylsulfosuccinate.
5. The process of claim 1 , wherein the acid compound or mixture of acid compounds comprises phosphoric acid.