High-surface precipitation silica acids

1. A precipitated silica which has the following properties:

BET surface area

200–300 m 2 /g,

CTAB surface area

≧170 m 2 /g,

DBP number

200–300 g/(100 g), and

Sears number V 2

23–35 ml/(5 g).

2. The precipitated silica as claimed in claim 1 , wherein the CTAB surface area is a maximum of 300 m 2 /g.

3. The precipitated silica as claimed in claim 1 which has a WK coefficient of <3.4 (ratio of the peak height of particles that are not broken-down by ultrasound in the size range 1.0-100 μm to the peak height of the broken-down particles in the size range <1.0 μm).

4. The precipitated silica as claimed in claim 1 , wherein the surface area of the precipitated silica is modified with an organosilane of Formula I to III:

[SiR 1 n (RO) r (Alk) m (Ar) p ] q [B]  (I),

SiR 1 n (RO) 3-n (Alkyl)   (II),

or

SiR 1 n (RO) 3-n (Alkenyl)   (III),

with the following meanings

B: —SCN, —SH, —Cl, —NH 2 , —OC(O)CHCH 2 , —OC(O)C(CH 3 )CH 2 —(if q=1) or - Sw- (if q=2), wherein B is chemically bonded to Alk,

R and R 1 : an aliphatic, olefinic, aromatic or arylaromatic radicals having 2 to 30 C atoms, which may optionally be substituted by the following groups: hydroxyl, amino, alcoholate, cyanide, thiocyanide, halogen, sulfonic acid, sulfonic acid ester, thiol, benzoic acid, benzoic acid ester, carboxylic acid, carboxylic ester, acrylate, methacrylate, organosilane radical, and where R and R 1 may have an identical or different meaning or substitution,

n: 0, 1 or 2,

Alk: a divalent unbranched or branched hydrocarbon radical having 1 to 6 carbon atoms,

m: 0 or 1,

Ar: an aryl radical having from 6 to 12 carbon atoms, which may be substituted by the following groups: hydroxyl, amino, alcoholate, cyanide, thiocyanide, halogen, sulfonic acid, sulfonic acid ester, thiol, benzoic acid, benzoic acid ester, carboxylic acid, carboxylic acid ester, acrylate, methacrylate, organosilane radical,

p: is 0 or 1, with the proviso that p and n are not simultaneously 0,

q: 1 or 2,

w: a number from 2 to 8,

r: 1, 2 or 3, with the proviso that r +n +m +p =4,

Alkyl: is a monovalent unbranched or branched saturated hydrocarbon radical with 1 to 20 carbon atoms, preferably 2 to 8 carbon atoms, and

Alkenyl: a monovalent unbranched or branched unsaturated hydrocarbon radical having from 2 to 20 carbon atoms.

5. A process for manufacture of a precipitated silica which has the following properties:

BET surface area

200–300 m 2 /g,

CTAB surface area

≧170 m 2 /g,

DBP number

200–300 g/100 g,

Sears number V 2

23–35 ml/(5 g);

comprising:

a) preparing an aqueous solution of an organic and/or inorganic salt and/or an alkali or alkaline-earth metal silicate and/or an organic and/or inorganic base having a pH ≧9;

b) simultaneously metering water glass and an acidifier into the aqueous solution with stirring at 55-95° C. for 10-120 minutes;

e) acidifying the aqueous solution of step (b) with an acidifier to a pH value of approx. 3.5, and

f) filtering and drying the acidified solution.

6. The process as claimed in claim 5 , wherein the concentration of the organic and/or inorganic salt in the aqueous solution is 0.01 to 5 mol/l.

7. The process as claimed in claim 5 or 6 , conducting the following steps (c) and (d) between steps b) and e);

c) stopping the metering in of the water glass and the acidifier for 30-90 minutes while the temperature is maintained; and

d) simultaneously metering in water glass and acidifier into the solution of step (d) with stirring at the temperature of 55-95° C. for 20-120 minutes.

8. The process as claimed in claim 7 , wherein the acidifier and/or water glass in steps b) and d) have the same concentration or metering rate.

9. The process as claimed in claim 7 , wherein the acidifier and/or water glass in steps b) and d) have a different concentration or metering rate.

10. The process as claimed in claim 9 , wherein in steps (b) and (d) the acidifier and the water glass are added in such a way that the metering rate of the two materials in step d) is 125-140% of the metering rate in step (b).

11. The process as claimed in claim 5 wherein the drying process is by an air-lift drier, a spray drier, a rack drier, a conveyor drier, a rotary drier, a flash drier, a spin flash drier or a nozzle drier.

12. The process as claimed in claim 5 wherein after the drying process a granulation process is conducted with a roller compactor.

13. The process as claimed in claim 5 , wherein during steps b) and/or d) an organic or inorganic salt is added to the solution.

14. The process as claimed in claim 5 , wherein the granulated or ungranulated precipitated silica is modified with organosilanes in mixtures of 0.5 to 50 parts relative to 100 parts precipitated silica where the reaction between precipitated silica and organosilane is conducted during the production of the mixture (in situ), or outside of production by spraying and subsequent tempering of the mixture, or by mixing of the organosilane and the silica suspension with subsequent drying and tempering.

15. Elastomer mixtures, vulcanizable rubber mixtures and vulcanizates, containing the precipitated silica as claimed in claim 1 .

16. Tires for high speed vehicles, the rubber of which contains the precipitated silica as a filler as claimed in claim 1 .

17. Tires for high speed vehicles, the rubber of which contains the precipitated silica as a filler as claimed in claim 1 .

18. The precipitated silica as claimed in claim 1 , wherein the Sears number V 2 has a value ranging from 26-35 ml/ (5 g).