Separator-electrode unit for lithium-ion batteries, method for the production and use thereof in lithium batteries
View Patent ↗The separator-electrode units comprise a porous electrode which is useful as a positive electrode (cathode) or negative electrode (anode) in a lithium battery and a separator layer applied to this electrode and are characterized in that the separator-electrode units comprise a purely inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal. More particularly, the separator layer comprises metal oxide particles having an average particle size (D g ) which is greater than the average pore size (d) of the pores of the porous positive electrode that are bonded together by metal oxide particles having a particle size (D k ) which is smaller than the pores of the porous electrode.
1. A separator-electrode unit capable of functioning in a lithium battery as a separator-electrode unit, the unit comprising a porous electrode and a separator layer applied to said porous electrode, wherein the separator-electrode unit comprises an inorganic separator layer which comprises at least two fractions of metal oxide particles which differ from each other in their average particle size and/or in the metal, the separator layer comprising metal oxide particles having an average particle size (D g ) which is greater than the average pore size (d) of the pores of the porous electrode that are adhered together by metal oxide particles having an average particle size (D k ) which is smaller than the pores of the porous electrode.
2. A separator-electrode unit according to claim 1 , wherein the separator layer has a thickness (z) which is less than 100 D g and not less than 1.5 D g .
3. A separator-electrode unit according to claim 1 , wherein the separator layer has a thickness (z) which is less than 20 D g and not less than 5 D g .
4. A separator-electrode unit according to claim 1 , wherein the metal oxide particles having an average particle size (D g ) which is greater than the average pore size (d) of the pores of the porous electrode are Al 2 O 3 and/or ZrO 2 particles.
5. A separator-electrode unit according to claim 1 , wherein the metal oxide particles having an average particle size (D k ) which is smaller than the average pore size (d) of the pores of the porous electrode are SiO 2 and/or ZrO 2 particles.
6. A separator-electrode unit according to claim 1 , wherein the metal oxide particles having an average particle size (D g ) which is greater than the average pore size (d) of the pores of the porous electrode have an average particle size (D g ) of less than 10 μm.
7. A separator-electrode unit according to claim 1 , wherein the separator layer comprises a coating with shutdown particles which melt at a desired shutdown temperature.
8. A separator-electrode unit according to claim 7 , wherein the shutdown particles have an average particle size (D w ) which is not less than the average pore size (d s ) of the pores of the porous separator layer.
9. A separator-electrode unit according to claim 7 , wherein the shutdown particle layer has a thickness (z w ) which ranges from about equal to the average particle size of the shutdown particles (D w ) up to 10 D w .
10. A separator-electrode unit according to claim 1 , wherein the separator layer has a porosity of from 30 to 70%.
11. A separator-electrode unit according to claim 1 , wherein the unit is bendable down to a radius of 50 cm without damage.
12. A separator-electrode unit according to claim 1 , wherein the electrode is an electrode which is capable of functioning as a positive electrode (cathode) or as a negative electrode (anode).
13. A lithium battery comprising said separator-electrode unit according to claim 1 .
14. A method for making a lithium battery, said method comprising:
incorporating said separator-electrode unit according to claim 1 in a battery comprising lithium to obtain said lithium battery.