Acidic hard surface cleaners
The present invention is directed to an acidic hard surface treatment composition which provides a cleaning and disinfecting benefit comprising: an acidic constituent which comprises water soluble organic acid; at least one anionic surfactant constituent; at least one nonionic surfactant constituent; at least one organic solvent constituent; optionally one or more further constituents and the balance, water. The compositions exhibit surprising efficacy against various gram positive and gram negative type pathogenic bacteria, as well as against fungi in the absence of known cationic quaternary ammonium compounds known to be effective against pathogenic bacteria, as well as other known-art antimicrobial constituents and bleach are excluded.
1. A hard surface treatment composition which provides a cleaning and disinfecting benefit consisting of:
an acidic constituent which comprises an acid selected from the group consisting of: citric acid, sorbic acid, acetic acid, boric acid, formic acid, maleic acid, adipic acid, lactic acid, malic acid, malonic acid, glycolic acid, and mixtures thereof;
at least one anionic surfactant constituent;
at least one nonionic surfactant constituent;
at least one organic solvent constituent wherein the organic solvent constituent consists solely of ethanol to the exclusion of other organic solvents;
optionally one or more further constituents selected from coloring agents, fragrances and fragrance solubilizers, viscosity modifying agents, pH adjusting agents and pH buffers including organic and inorganic salts, opacifying agents, hydrotropes, antifoaming agents, enzymes, anti-spotting agents, anti-oxidants, preservatives, and anti-corrosion agents;
and the balance, water
characterized in that:
cationic quaternary ammonium compounds known to be effective against gram positive and/or gram negative type pathogenic bacteria, other known-art antimicrobial constituents selected from non-cationic phenolic based antimicrobials; para-chloro-meta-xylenol; resorcinol and derivatives thereof; bisphenolic compounds; halogenated carbanilides; 2-hydroxydiphenyl compounds; pyrithiones; hydantoin compounds; iodophors and bleach are excluded.
2. A composition according to claim 1 wherein the acid constituent consists essentially of an acid selected from the group consisting of: citric acid, sorbic acid, acetic acid, boric acid, formic acid, maleic acid, adipic acid, lactic acid, malic acid, malonic acid, glycolic acid, and mixtures thereof.
3. A composition according to claim 1 wherein the pH is from about 1 to about 5.
4. A composition according to claim 3 wherein the pH is from about 1 to 4.
5. A composition according to claim 4 wherein the pH is from about 1 to about 3.
6. A composition according to claim 1 wherein the anionic surfactant is a sulfonate.
7. A composition according to claim 2 wherein the acid constituent consists essentially of an acid selected from the group consisting of: citric acid in the absence of further organic acids, or a mixture of citric acid and lactic acid in the absence of further organic acids.
8. A composition according to claim 1 wherein the composition achieves a log reduction of at least 6 for a 5 minute contact time according to the Quantitative Surface Test of the prEN 13697 protocol against one or more of the challenge organisms: Staphylococcus aureus (ATTC 6538); Escherichia coli (ATCC 10536) Enterococcus hirae (ATCC 10541) and Pseudomonas aeruginosa (ATCC 15442).