Pyrogenically produced silica
View Patent ↗Pyrogenically produced silica powder with a BET surface of 30 to 90 m 2 /g, a dibutyl phthalate number of at least 80 and a tamped density of no more than 110 g/l. It is produced in that at least one vaporous silicon compound, a gas containing free oxygen and a combustible gas are mixed together in a closed burner and then burnt in a flame in the flame tube of the burner, the solid obtained is separated from the gas mixture and optionally purified, wherein the oxygen content of the gas containing free oxygen is adjusted such that the lambda value is greater than or equal to 1, and the gamma value is between 1.2 and 1.8. It can be used in toner applications.
1. A pyrogenically produced silica powder comprising particles each having a homogenous composition, wherein the pyrogenically produced silica powder has a BET surface of 30 to 90 m 2 /g, a DBP number of at least 80, expressed as g of dibutyl phthalate/100 g of silica and a tamped density of no more than 110 g/l, wherein the particles consist of silica.
2. The pyrogenically produced silica powder according to claim 1 , wherein the average aggregate circumference is at least 1000 nm.
3. The pyrogenically produced silica powder according to claim 1 , wherein the kurtosis of the aggregate area is at least 20.
4. The pyrogenically produced silica powder according to claim 1 , wherein the pyrogenically produced silica powder has a pH value, measured in a 4 per cent aqueous dispersion, of between 3.8 and 5.
5. The pyrogenically produced silica powder according to claim 1 , wherein
the BET surface is 35 to 55 m 2 /g,
the DBP number is 100 to 130 g dibutyl phthalate/100 g silicon dioxide,
and the pH value, measured in a 4% aqueous dispersion, is 4.3 to 4.8.
6. A process for the production of the silica powder of claim 1 , wherein at least one vaporous silicon compound, a gas containing free oxygen (primary air) and a combustible gas are mixed together in a closed burner and then burnt in a flame in the flame tube of the burner, the solid obtained is separated from the gas mixture and optionally purified, wherein
the oxygen content of the gas containing free oxygen is adjusted such that the lambda value is greater than or equal to 1, and
the gamma value is between 1.2 and 1.8.
7. The process according to claim 6 , wherein 1≦lambda≦1.2.
8. The process according to claim 6 , wherein in addition, secondary air is introduced into the flame tube, secondary air/primary air being ≦1.1.
9. The process according to claims 6 , wherein the proportion of oxygen in the gas containing free oxygen is between 30 and 40 vol. %.
10. The process according to claim 6 , wherein silicon halides, organochlorosilicon compounds or organosilicon compounds and mixtures of the above compounds are used as the silicon compound.
11. The process according to claim 6 , wherein 1≦lambda≦1.2, 1.2≦gamma≦1.8, the ratio of secondary air/primary air is ≦1.1 and the proportion of oxygen in the gas containing free oxygen is between 30 and 40 vol. % and the silicon compound is silicon tetrachloride.
12. A method for adjusting the rheology of a liquid system comprising adding the pyrogenically produced silica powder as claimed in claim 1 to a liquid.
13. The pyrogenically produced silica powder according to claim 1 , wherein the powder consists of silica.