Anode and battery, and manufacturing methods thereof
View Patent ↗An anode and a battery capable of realizing a high capacity and improving charge and discharge cycle characteristics, and manufacturing methods thereof are provided. An anode active material layer contains a particulate anode active material including a simple substance or a compound of an element capable of forming an alloy with Li, a particulate binder including a copolymer of vinylidene fluoride or polyvinylidene fluoride, and a conductive agent. The anode active material layer is formed by using a dispersion medium having a swelling degree of 10% or less to the binder, specifically pure water or the like. The particulate binder functions as a cushion to absorb expansion and shrinkage of the anode active material due to charge and discharge, and lowering of electron conductivity caused by generation of cracks or separation is prevented. Further, since the anode active material is not covered with the binder, electrode reaction is well performed.
1. An anode, comprising:
a particulate anode active material;
a conductive agent, and
a particulate binder containing at least one compound selected from the group consisting of copolymers including vinylidene fluoride and polyvinylidene fluoride,
wherein the binder is not dissolved in a dispersion medium and is fused by heating such that the anode active material and the conductive agent are prevented from being covered with the binder.
2. An anode according to claim 1 , wherein an average particle diameter of the binder ranges from about 30 μm or less.
3. An anode according to claim 1 , wherein the anode active material includes at least one substituent selected from the group consisting of one or more simple substances of elements capable of forming an alloy with lithium and compounds thereof.
4. An anode according to claim 1 , which is formed by using an anode mixture slurry that includes: the anode active material; the binder; and a dispersion medium having a swelling degree of about 10% or less to the binder.
5. An anode according to claim 4 , which is formed by using an anode mixture slurry, wherein at least the binder is dispersed in the dispersion medium, and then the anode active material is dispersed.
6. An anode according to claim 4 , which is formed by using an anode mixture slurry, wherein an average particle diameter of the binder is about 30 μm or less.
7. The anode of claim 1 , wherein the binder is fused by heating to at least about the melting point of the binder.
8. The anode of claim 1 , wherein the binder is fused by heating to at least about 180° C.
9. The anode of claim 1 , wherein the binder is fused by heating to at least about 200° C.