Process and plant for the manufacture of sulphuric acid from gases rich in sulphur dioxide
View Patent ↗The present invention is concerned with a process and a plant for the production of sulphuric acid wherein a sulphur dioxide-containing feed gas is converted, at least in part, with oxygen in at least two contact stages of main contacts arranged in series, to generate sulphur trioxide, and wherein generated sulphur trioxide-containing gas is conducted to an absorber and converted therein to sulphuric acid. In order to be able to economically process feed gases of a sulphur dioxide content of between 13 and 66% by volume to sulphuric acid, using conventional catalysts, it is suggested to withdraw from a contact stage connected upstream of the last main contact stage, a partial stream of the sulphur dioxide- and sulphur trioxide-containing gas, to mix the said partial stream with the feed gas to generate a contact gas of a sulphur dioxide content of more than 13% by volume, and to return the same to the first contact stage.
1. A process for the production of sulphuric acid, comprising reacting a sulphur dioxide-containing feed gas, at least in part, with oxygen in at least two contact stages of main contacts, arranged in series, to generate sulphur trioxide, feeding the generated sulphur trioxide-containing gas to an absorber and reacting said sulphur trioxide-containing gas therein to form sulphuric acid, withdrawing a partial stream of the sulphur dioxide and sulphur trioxide-containing gas from a contact stage located upstream of the last main contact stage, mixing said partial stream with the feed gas to form a contact gas having a sulphur dioxide content of more than 13% by volume, and returning said mixed partial stream to the first contact stage, wherein the contact stages contain a catalyst and wherein the partial stream withdrawn from the contact stage located upstream of the last main contact stage has a sulphur trioxide content of from about 9% by volume to about 21% by volume.
2. The process according to claim 1 , wherein the contact gas has a sulphur dioxide content of between 14 and 25% by volume.
3. The process according claim 1 , wherein air and/or technical oxygen is supplied to the feed gas prior to being mixed with the partial stream, and wherein the O 2 to SO 2 ratio in the contact gas, based on the volumetric portions thereof, is adjusted to less than 1.2.
4. The process according to claim 3 , wherein the volumetric portion of the partial stream supplied to the feed gas amounts to between 15 and 35% of the contact gas.
5. The process according to claim 1 , further comprising providing a pre-contact upstream from the main contact to which the contact gas is fed, withdrawing a process gas containing no more than 13% by volume of sulphur dioxide from the pre-contact, and supplying said process gas to the first contact stage of the main contact.
6. The process according to claim 5 , wherein the pre-contact comprises one or two pre-contact stages.
7. The process according to claim 5 , wherein the process gas discharged from the pre-contact, prior to being introduced into the main contact is passed through a pre-absorber.
8. The process according to claim 5 , wherein the process gas discharged from the first main contact, prior to being introduced into the second main contact is supplied to an intermediate absorber.
9. The process according to claim 5 , wherein the process gas discharged from the second main contact is supplied to a final absorber.
10. The process according to claim 5 , further comprising conducting at least part of the process gas discharged from the pre-contact via a bypass line past a pre-absorber directly into the main contact.
11. The process according to claim 9 , wherein the gas discharged from the final absorber is subjected to gas scrubbing with hydrogen peroxide, ammonia or sodium hydroxide forming the neutralizing agent for the sulphur dioxide.
12. The process according to claim 9 , wherein the partial stream, prior to being returned to the first contact stage, is cooled to a temperature of less than 500° C.
13. The process according to claim 9 , wherein the amount of the gas re-circulated as the partial stream is adjusted on the basis of the temperature at which the gas leaves the first contact stage.
14. A process for the production of sulphuric acid, comprising reacting a sulphur dioxide-containing feed gas, at least in part, with oxygen in at least two contact stages of main contacts, arranged in series, to generate sulphur trioxide, feeding the generated sulphur trioxide-containing gas to an absorber and reacting said sulphur trioxide-containing gas therein to form sulphuric acid, withdrawing a partial stream of the sulphur dioxide and sulphur trioxide-containing gas from a contact stage located upstream of the last main contact stage, wherein the partial stream has a sulphur trioxide content of from about 9% by volume to about 21% by volume, mixing said partial stream with the feed gas so as to form a partial stream and feed gas mixture having a sulphur dioxide content of more than 13% by volume and feeding the mixture into a pre-contact upstream from the main contact, withdrawing a process gas from the pre-contact, and supplying said process gas to the first contact stage of the main contact, wherein the contact stages and the pre-contact contain a catalyst.
15. The process according to claim 14 , wherein the process gas contains no more than 13% by volume of sulphur dioxide.
16. The process according claim 14 , wherein at least one of air and technical oxygen is supplied to the feed gas prior to being mixed with the partial stream, and wherein the O 2 to SO 2 ratio in the partial stream and feed gas mixture, based on the volumetric portions thereof, is adjusted to less than 1.2.
17. The process according to claim 16 , wherein the volumetric portion of the partial stream supplied to the feed gas amounts to between 15 and 35% of the partial stream and feed gas mixture.