IP Library Granted Patent US 7,780,802
Granted Patent B2
US 7,780,802 · App. 10/534,006 · Granted Aug 24, 2010

Simplified method for making rolled Al—Zn—Mg alloy products, and resulting products

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 7,780,802
App. No.
10/534,006
Granted
Aug 24, 2010
Kind
B2
Abstract

A process for making Al—Zn—Mg alloy products, and products formed according to such processes are disclosed. The present invention provides a product having an improved compromise between mechanical characteristics and corrosion strength.

Claims (38)

1. A process for generating an intermediate laminated product in an aluminum alloy of the Al—Zn—Mg type, said process consisting of:

a) generating a plate by semi-continuous casting, the plate containing (in percentages per unit mass):

Mg 0.5-2.0, Mn<1.0, Zn 3.0-9.0, Si<0.50, Fe<0.50, Cu<0.50, Ti<0.15, Zr<0.20

the remainder aluminum with inevitable impurities, in which Zn/Mn>1.7;

b) subjecting said plate to homogenization or reheating to a temperature T 1 , selected so that 500° C.≦T 1 ≦(T s −20° C.), where T s is the alloy burning temperature;

c) conducting an initial hot-rolling step including one or more roll runs on a hot rolling mill, an input temperature T 2 of the initial hot rolling step being selected such that (T 1 −60° C.)≦T 2 ≦(T 1 −5° C.), and the rolling process being conducted in such a way that the output temperature T 3 in such that (T 1 −150° C.)≦T 3 ≦(T 1 −30° C.) and T 3 ≦T 2 ;

d) cooling a strip emerging from said initial hot-rolling step to a temperature T 4 ;

e) conducting a second hot-rolling step on said strip at an input temperature T 5 , the input temperature T 5 being selected such that T 5 ≦T 4 and 200° C.≦T 5 ≦300° C., and the second hot-rolling process being conducted in such a way that the coiling temperature T6 is such that (T 5 −150° C.)≦T 6 ≦(T 5 −20° C.);

f) optionally conducting at least a cold-rolling, aging treatment, and/or cutting operation;

wherein the yield strength Rp0.2 of said laminated product is at least 250 MPa, the fracture strength Rm of said laminated product is at least 280 MPa, and the elongation at fracture of said laminated product is at least 8%.

2. A process according to claim 1 , wherein the zinc content of the alloy is between from 4.0 to 6.0%, the Mg content is from 0.7 to 1.5%, and the Mn content is less than 0.60%.

3. A process according to claim 2 , wherein Cu<0.25%.

4. A process according to claim 2 , wherein the alloy is selected from the group consisting of alloys 7020, 7108, 7003, 7004, 7005, 7008, 7011, and 7022.

5. A process according to claim 1 , wherein said intermediate laminated product has a thickness from 3 mm to 12 mm.

6. A process according to claim 1 , wherein said intermediate laminated product is subjected to cold working reduction from 1% to 9%, and/or to an additional heat treatment including one or more points at temperatures between from 80° C. to 250° C., said additional heat treatment being able to occur before, after or during said cold working.

7. A process according to claim 1 , wherein the temperature T 3 is such that (T 1 −100° C.)≦T 3 ≦(T 1 −30° C.) and/or the temperature T 2 is such that (T 1 −30° C.)≦T2≦(T 1 −5° C.).

8. A process according to claim 1 , wherein the temperature T 3 is greater than a solvus temperature of the alloy.

9. A process according to claim 1 , wherein the alloy is a 7108 alloy and the temperatures T 1 to T 6 are respectively T 1 =550° C., T 2 =540° C., T 3 =490° C., T 4 =270° C., T 5 =270° C., T 6 =150° C.

10. A process according to claim 1 , wherein heat treatment operations are carried out on-line, without any heat treatments being carried out separately.

11. A process according to claim 1 , wherein each step of said process is conducted at a lower temperature than the temperature of a previous step.

12. A process of claim 1 wherein said yield strength R p0.2 is at least 290 MPa and said fracture strength R m is at least 330 MPa.

13. A process of claim 1 , wherein Zn: 4.0-6.0%, Mg 0.7-1.5%, Mn<0.60%, Cu<0.25% and wherein a width of the precipitation-free zones at grain boundaries thereof of said laminated product is at least 100 nm.

14. A process of claim 1 , wherein Zn: 4.0-6.0%, Mg 0.7-1.5%, Mn<0.60%, Cu<0.25% and wherein MgZn 2 type precipitations at grain boundaries of said laminated product have an average size of at least 150 nm.

15. A process for generating an intermediate laminated product in an aluminum alloy of the Al—Zn—Mg type, said process consisting of:

a) generating a plate by semi-continuous casting, the plate containing (in percentages per unit mass):

Mg 0.5-2.0, Mn<1.0, Zn 3.0-9.0, Si<0.50, Fe<0.50, Cu<0.50, Ti<0.15, Zr<0.20, and at least one element selected from the group consisting of Sc, Y, La, Dy, Ho, Er, Tm, Lu, Hf, and Yb with a concentration not exceeding the following values:

Sc<0.50%,

Y<0.34%,

La, Dy, Ho, Er, Tm, Lu<0.10% each,

Hf<1.20%,

Yb<0.50%,

the remainder aluminum with inevitable impurities, in which Zn/Mn>1.7;

b) subjecting said plate to homogenization or reheating to a temperature T 1 , selected so that 500° C.≦T 1 ≦(T s ≦20° C.), where T s is the alloy burning temperature;

c) conducting an initial hot-rolling step including one or more roll runs on a hot rolling mill, an input temperature T 2 of the initial hot rolling step being selected such that (T 1 −60° C.)≦T 2 ≦(T 1 −5° C.), and the rolling process being conducted in such a way that the output temperature T 3 in such that (T 1 −150° C.)≦T 3 ≦(T 1 −30° C.) and T 3 ≦T 2 ;

d) cooling a strip emerging from said initial hot-rolling step to a temperature T 4 ;

e) conducting a second hot-rolling step on said strip at an input temperature T 5 , the input temperature T 5 being selected such that T 5 ≦T 4 and 200° C.≦T 5 ≦300° C., and the second hot-rolling process being conducted in such a way that the coiling temperature T6 is such that (T 5 −150° C.)≦T 6 ≦(T 5 −20° C.);

f) optionally conducting at least a cold-rolling, aging treatment, and/or cutting operation;

wherein the yield strength Rp0.2 of said laminated product is at least 250 MPa, the fracture strength Rm of said laminated product is at least 280 MPa, and the elongation at fracture of said laminated product is at least 8%.

Assignments (4)
CHANGE OF NAME Recorded Oct 21, 2016
From: CONSTELLIUM FRANCE SAS
To: CONSTELLIUM ISSOIRE
Reel/Frame 040462/0735 →
CHANGE OF NAME Recorded Jan 5, 2012
From: ALCAN RHENALU
To: CONSTELLIUM FRANCE
Reel/Frame 027489/0240 →
CHANGE OF NAME Recorded May 13, 2009
From: PECHINEY RHENALU
To: ALCAN RHENALU
Reel/Frame 022679/0118 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2005
From: DIF, RONAN; EHRSTROM JEAN-CHRISTOPHE; GRANGE, BERNARD; HOCHENEDEL, VINCENT; RIBES, HERVE
To: RHENALU, PECHINEY
Reel/Frame 016683/0586 →