High-pressure discharge lamp with mercury chloride having a limited chlorine content
View Patent ↗The invention relates to a high-pressure discharge lamp with a discharge vessel having a filling comprising—a rare gas, for example argon, —mercury, and —chlorine, wherein the filling quantities of mercury [Hg] and chlorine [Cl] comply with the following conditions: —[Hg](E[Cl] 3 200 (μmole/cm3)2, —[Cl] £ 10 μmole/cm3. The condition [Hg](E[Cl] 3 200 (μmole/cm3)2 achieves HgCl vapor pressures in the discharge sufficient for generating significant radiation components of the B2S+-X2S+ band system of this molecule. The condition [Cl] £ 10 μmole/cm3 serves to limit the chemical aggressiveness of the chlorine filling, in particular to limit the attacks on the wall and electrodes and thus to achieve longer lamp lives. The addition of chlorine-binding metals, in particular of germanium, leads to a further improvement in the radiation and life properties of the lamp.
1. A high-pressure discharge lamp with a discharge vessel having a filling comprising: a rare gas, mercury, and chlorine, wherein the discharge vessel is elliptical in shape, is made of quartz, and has an inner diameter of 11 mm and an inner length of 16 mm, the high-pressure discharge lamp further comprising tungsten electrodes for coupling electrical power into the high-pressure discharge lamp, and the filling further comprises 4.2 μmole/cm 3 argon, 375 μmole/cm 3 mercury, 1.8 μmole/cm 3 chlorine, and 2.5 μmole/cm 3 germanium.
2. The high-pressure discharge lamp as claimed in claim 1 , wherein the filling further comprises a metal that forms more stable chloride compounds than does the mercury, said metal being chosen from the group of aluminum, arsenic, bismuth, cobalt, gallium, germanium, indium, lead, tin, thallium, and vanadium as a chlorine binder.
3. The high-pressure discharge lamp as claimed in claim 2 , wherein a sum [M] of the filling quantities of metals that are
chlorine-binding complies with the condition: [M]/[Cl]≧1/W M , where W M denotes average valency of the metals that are chlorine-binding.
4. The high-pressure discharge lamp as claimed in claim 1 , wherein the filling comprises germanium as a chlorine-binding metal.
5. The high-pressure discharge lamp as claimed in claim 1 , wherein the discharge vessel is made of quartz or an oxidic ceramic material.
6. The high-pressure discharge lamp as claimed in claim 1 , further comprising, for coupling electrical power into the high-pressure discharge lamp: tungsten electrodes, or composite tungsten and rhenium electrodes, or coated electrodes formed by a tungsten core and a coating comprising at least 90% by weight of rhenium.
7. A lighting unit comprising the high-pressure discharge lamp as claimed in claim 1 .
8. The lighting unit as claimed in claim 7 , further comprising, for coupling electrical power into the high-pressure discharge lamp: a generator for generating an electromagnetic alternating field in a range of 0.5 to 500 MHz or 500 MHz to 50 GHz.
9. The high-pressure discharge lamp of claim 1 , wherein the discharge vessel is made of densely sintered aluminum oxide.
10. A high-pressure discharge lamp comprising:
a discharge vessel having a ratio of an inner diameter to an inner length of substantially 11/16;
electrodes for coupling electrical power into the high-pressure discharge lamp; and
a filling in the discharge vessel, wherein the filling comprises argon, mercury, chlorine and germanium in proportions with each other that substantially comply with 4.2 μmole/cm 3 of the argon, 375 μmole/cm 3 of the mercury, 1.8 μmole/cm 3 of the chlorine, and 2.5 μmole/cm 3 of the germanium.
11. The high-pressure discharge lamp of claim 10 , wherein a sum [M] of the filling quantities of metals that are chlorine-binding complies with the condition:
[M]/[Cl]≧1/W M , where W M denotes average valency of the metals that are chlorine-binding.
12. The high-pressure discharge lamp of claim 10 , wherein the discharge vessel is made of quartz or an oxidic ceramic material.
13. The high-pressure discharge lamp of claim 10 , wherein the discharge vessel is made of densely sintered aluminum oxide.
14. The high-pressure discharge lamp of claim 10 , further comprising electrodes made of at least one of tungsten electrodes, rhenium electrodes, and coated electrodes formed by a tungsten core and a coating comprising at least 90% by weight of rhenium.