Method for producing alkaline earth sulphate nanoparticles
View Patent ↗The invention relates to synthesis of nanoparticles, in particular to methods for producing nanoparticles with networks consisting of Z sulphate (Z=magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba) or the binary mixtures thereof). The inventive method consists in synthesising the nanoparticles by crystal growth from an ion Z source and a sulphate ion source in a liquid phase mixture. The invention produces Z sulphate nanoparticles having a small diameter and uniformly dispersible in water or other solvents in a simple way. Co-ordinating solvents like glycerine, glycol ethylene and other polyethylene glycols, polyalcohols or dimethylsulphoxide (DMSO) are used for the synthesis mixture.
1. Nanoparticles having a crystal lattice or, in the case of doping, a host lattice essentially consisting of Z sulphate (Z=magnesium (Mg), calcium (Ca), strontium (Sr) or barium (Ba)), which can be obtained by synthesis under controlled crystal growth in a non-aqueous solvent with coordinating properties, the nanoparticles having an average particle size of 0.2 to 50 nanometres and the property that they are dispersible in water.
2. A method for producing nanoparticles having a crystal lattice or, in the case of doping, a host lattice essentially consisting of Z sulphate (Z=magnesium (Mg), Z=calcium (Ca), strontium (Sr) or barium (Ba)), in which the nanoparticles are synthesised by crystal growth from a Z ion source and a sulphate ion source in a liquid phase synthesis mixture, characterized in that the synthesis mixture contains a non-aqueous solvent with coordinating properties which acts as a control component for particle growth and characterized in that said nanoparticles have an average particle size of 0.2 to 50 nanometers and are dispersible in water.
3. The method according to claim 2 , characterized in that glycerin, ethylene glycol, polyethylene glycols, polyalcohols or dimethyl sulfoxide (DMSO) is used as the non-aqueous solvent with coordinating properties.
4. The method according to claim 3 , wherein combinations of the non-aqueous solvent with coordinating properties are used.
5. The method according to claim 2 , 3 or 4 , wherein to synthesize doped Z sulphate nanoparticles, an alkaline-acting component is added to the synthesis mixture.
6. The method according to claim 5 , wherein dimethyl sulfoxide (DMSO) is used as the non-aqueous solvent with coordinating properties for synthesizing manganese- and europium (II)-doped Z sulphate nanoparticles and imidazole is added as alkaline-acting component.
7. The method according to claim 2 , wherein the synthesis mixture furthermore contains a non-coordinating solvent.
8. The method according to claim 7 , wherein most of the solvent of the synthesis mixture has coordinating properties.
9. The method according to claim 2 , wherein one or more of: tetrabutylammonium hydrogen sulphate, bis(trimethylsilyl) sulphate, ammonium hydrogen sulphate, ammonium sulphate, alkali sulphates, alkali hydrogen sulphates, amantadine sulphate, ethylenediammonium sulphate and hyrazinium sulphate is used as the sulphate ion source.
10. The method according to claim 2 , further comprising the following after-treatment step:
heating the synthesised nanoparticles in the presence of a modification molecule to modify the surface of said synthesized nanoparticles, wherein the modification molecule is selected from the following group:
a phosphate, an amine, a phosphonate, a phosphine, a phosphine oxide, a carboxylic acid, alcohols, glycerin, ethylene glycol, polyglycols, organic esters, silanes, siloxanes, organic sulfones, organic ketones, organic nitriles, organic sulfoxides, organic amides and perfluorinated modifications of the aforementioned substances.
11. The method according to claim 5 , wherein the alkaline-acting component is an amine.
12. The method according to claim 11 , wherein the amine is trioctylamine.
13. The method according to claim 5 , wherein the alkaline-acting component is imidazole.
14. The nanoparticles, according to claim 1 , wherein the non-aqueous solvent with coordinating properties is glycerin, ethylene glycol, polyethylene glycol, polyethylene glycols, polyalcohol or dimethyl sulfoxide (DMSO).
15. The nanoparticles according to claim 14 , wherein ethylene glycol is used as the non-aqueous solvent with coordinating properties.