Fabric treatment
View Patent ↗A method of treating finished garments comprising cellulosic material so as to cause cross-linking, which comprises the step of treating fabrics with an effective amount of a blocked cross-linking agent for cellulose, the cross-linking agent being thermally activated.
1. A method of treating finished garments comprising cellulosic material so as to cause cross-linking, which comprises the step of treating fabrics with an effective amount of a blocked cross-linking agent for cellulose, said cross-linking agent being thermally activated, wherein the blocked cross-linking agent comprises a polycarboxylic acid, which is blocked by esterification with an electron withdrawing alcohol or imide to form a polyester and wherein the blocking alcohol or imide comprises one or more of:
a) trichlorophenol,
b) isoeuginol,
c) menthol,
d) 4-cyanophenol,
e) ethyl salicylate,
f) 2,6-dimethoxy phenol,
g) 4-aminophenol,
h) dimethylamino phenol, and,
i) N-hydroxysuccinimide.
2. A method according to claim 1 wherein the polycarboxylic acid is succinic acid, butyl tetra carboxylic acid (BTCA), 3,6-dioxaoctanedioic acid, tartaric acid, mucic acid, glutamic acid, methylamino diacetic acid, or nitriloacetic acid.
3. A method according to claim 1 wherein the polyester comprises one or more of:
a) trichlorophenol diester of succinic acid,
b) trichlorophenol diester of BTCA,
c) N-hydroxysuccinimide diester of succinic acid,
d) isoeugenol diester of succinic acid, and,
e) menthol diester of succinic acid.
4. A method according to claim 1 which further comprises the step of heat curing the cellulosic material.
5. A method according to claim 4 wherein heat treatment is performed at a temperature of from 50 to 250° C., more preferably at a temperature of from 100–200° C.
6. A method accord to claim 1 wherein the cross-linking agent has a molecular weight below 1500 Dalton.