IP Library Granted Patent US 8,258,232
Granted Patent B2
US 8,258,232 · App. 10/539,792 · Granted Sep 4, 2012

Transparent acrylate adhesive mass comprising a filler

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Quick Facts
Patent No.
US 8,258,232
App. No.
10/539,792
Granted
Sep 4, 2012
Kind
B2
Abstract

Transparent acrylate pressure-sensitive adhesive comprising a filler, the acrylate-pressure sensitive adhesive comprising a polyacrylate and particles of silicate and/or of silica gel. The particles of silicate and/or of silica gel have a size of not more than 50 nm. The acrylate pressure-sensitive adhesive is prepared by a process in which acrylates and comonomers are polymerized in the presence of at least one organic solvent or in bulk, the particles of silicate and/or of silica gel being mixed in before or after the polymerization.

Claims (20)

1. A transparent acrylate pressure-sensitive adhesive comprising a polyacrylate and a filler, wherein the filler comprises particles of silicate and/or of silica gel, wherein said particles additionally comprise a coating of polyacrylate chemically bonded to a free radical initiator which free-radical initator is chemically bonded to said silicate and/or silica gel, and wherein the polyacrylate-coated particles of silicate and/or of silica gel have a size of not more than 50 nm.

2. The acrylate pressure-sensitive adhesive of claim 1 , wherein the polyacrylate-coated particles of silicate and/or of silica gel have a size of 10 to 30 nm.

3. The acrylate pressure-sensitive adhesive of claim 1 , wherein the polyacrylate-coated particles of silicate and/or of silica gel are present with a weight fraction of 0.5 to 25 relative to unfilled silicate/silica gel.

4. The acrylate pressure-sensitive adhesive of claim 1 , wherein the polyacrylate is obtained from a comonomer composition comprising:

a) acrylic acid and methacrylic acid derivatives of the formula (I), with a fraction of 70 to 100 percent by weight,

CH 2 ═C(R 1 )(COOR 2 )  (I)

where R 1 ═H or CH 3 and R 2 ═H or an alkyl chain having 2 to 20 carbon atoms, or stearyl(meth)acrylate or (meth)acrylic acid, and

b) vinyl compounds comprising functional groups, with a fraction of 0 to 30 percent by weight.

5. The acrylate pressure-sensitive adhesive of claim 4 , wherein the vinyl compound is a maleic anhydride, a styrene, a styrene compound, a vinyl acetate, a (meth)acrylamide, an N-substituted (meth)acrylamide, β-acryloyloxypropionic acid, a vinyl acetic acid, a fumaric acid, a crotonic acid, an aconitic acid, a dimethylacrylic acid, a trichloroacrylic acid, an itaconic acid, a hydroxyalkyl(meth)acrylate, an amino-containing (meth)acrylate, a hydroxyl-containing (meth)acrylate, a 2-hydroxyethyl(meth)acrylate, a 2-hydroxypropyl(meth)acrylate, and/or a 4-hydroxybutyl(meth)acrylate.

6. The acrylate pressure-sensitive adhesive of claim 4 , wherein the vinyl compound is a double-bond-functionalized photoinitiator.

7. The acrylate pressure-sensitive adhesive of claim 1 , wherein the polyacrylate of the pressure-sensitive adhesive and of the polyacrylate-coated particle coating are identical.

8. A process for preparing an acrylate pressure-sensitive adhesive of claim 1 , said process comprising polymerizing the acrylates and comonomers in the presence of at least one organic solvent or in bulk, the polyacrylate-coated particles of silicate and/or of silica gel being mixed in.

9. The process of claim 8 , wherein polyacrylate-coated particles of silicate and/or of silica gel having a maximum size of 50 nm are mixed in.

10. The process of claim 8 , wherein the polyacrylate-coated particles of silicate and/or of silica gel are mixed in with a weight fraction of 0.5 to 25 relative to unfilled silicate/silica gel.

11. The process of claim 8 , wherein the polyacrylate-coated particles of silicate and/or of silica gel are mixed in during or after the polymerization.

12. The process of claim 8 , wherein the polyacrylate of the acrylate pressure-sensitive adhesive and of the polyacrylate-coated particle coating are identical.

13. The process of claim 8 , which further comprises crosslinking the acrylate pressure-sensitive adhesive by UV irradiation in the range from 200 to 400 nm.

14. The process of claim 13 , wherein the acrylate pressure-sensitive adhesive is crosslinked by ionizing radiation or by thermal crosslinking.

15. A pressure-sensitive adhesive tape comprising the acrylate pressure-sensitive adhesive of claim 1 .

16. A bonding method comprising applying a pressure-sensitive adhesive tape of claim 15 to a substrate.

Assignments (3)
CHANGE OF ADDRESS Recorded Dec 17, 2015
From: TESA SE
To: TESA SE
Reel/Frame 037317/0675 →
CHANGE OF NAME Recorded Oct 7, 2010
From: TESA AG
To: TESA SE
Reel/Frame 025105/0146 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 9, 2006
From: HUSEMANN, MARC; ZOLLNER, STEPHAN
To: TESA AG
Reel/Frame 017919/0653 →