Vinyl polymer, process for producing vinyl polymer, thermosetting coating composition, and coating material
View Patent ↗A vinyl-based polymer having a mass average molecular weight of 1500 to 10000, which is prepared by a first step of continuously feeding a material mixture containing a vinyl-based monomer to a continuous tank type first reactor, and polymerizing the vinyl-based monomer under the conditions of a polymerization temperature of 150° to 300° C. and a retention time of 1 to 60 minutes at a rate of polymerization of 50 to 99% to obtain a reaction intermediate mixture; and a second step of feeding a polymerization initiator in the amount of 0.01 to 5 parts by mass based on 100 parts by mass of the vinyl-based monomer and the reaction intermediate mixture to a second reactor, and further polymerizing the vinyl-based monomer under the conditions of a polymerization temperature of 100° to 200° C. and a retention time of 10 to 240 minutes at a rate of polymerization of 80% or more.
1. A method for producing a vinyl-based polymer, comprising the steps of:
a first step of continuously feeding a material mixture comprising a vinyl-based monomer and a solvent selected from the group consisting of aromatic hydrocarbons, ketones, esters, alcohols, and mixtures thereof, to a continuous tank first reactor and polymerizing the vinyl-based monomer under conditions of a polymerization temperature of 150° to 300° C. and a retention time of 1 to 60 minutes at a rate of polymerization of 50 to 99% to obtain a reaction intermediate mixture, wherein the material mixture is continuously fed to the first reactor after preheating; and
a second step of feeding a polymerization initiator in the amount of 0.01 to 5 parts by mass based on 100 parts by mass of the vinyl-based monomer and the reaction intermediate mixture to a second reactor, and further polymerizing the vinyl-based monomer under conditions of a polymerization temperature of 100° to 200° C. and a retention time of 10 to 240 minutes at a rate of polymerization of 80% or more.
2. The method for producing a vinyl-based polymer according to claim 1 , wherein a resulting polymer has a mass average molecular weight of 1500 to 10000.
3. The method for producing a vinyl-based polymer according to claim 1 , wherein the material mixture contains the polymerization initiator in an amount of 0.01 to 12 parts by mass based on 100 parts by mass of the vinyl-based monomer.
4. The method for producing a vinyl-based polymer according to claim 3 , wherein the polymerization initiator is used in an amount of 0.01 to 8 parts by mass based on 100 parts by mass of the vinyl-based monomer.
5. The method for producing a vinyl-based polymer according to claim 1 , wherein the material mixture contains a solvent in an amount of 200 parts by mass or less based on 100 parts by mass of the vinyl-based monomer.
6. The method for producing a vinyl-based polymer according to claim 5 , wherein a content of the solvent is 2 to 100 parts by mass based on 100 parts by mass of the vinyl-based monomer.
7. The method for producing a vinyl-based polymer according to claim 1 , wherein the polymerization temperature in the first step is 200° to 280° C.
8. The method for producing a vinyl-based polymer according to claim 1 , wherein the rate of polymerization in the first step is 80 to 98%.
9. The method of claim 1 , wherein the solvent is selected from the group consisting of aromatic hydrocarbons, ketones, and mixtures thereof.
10. The method of claim 1 , wherein the solvent is selected from the group consisting of aromatic hydrocarbons, ketones, alcohols, and mixtures thereof.
11. The method of claim 1 , wherein the solvent is selected from the group consisting of aromatic hydrocarbons, ketones, esters, and mixtures thereof.