Exhaust gas aftertreatment installation and method
View Patent ↗An exhaust gas aftertreatment installment and associated exhaust gas aftertreatment method utilizes a nitrogen oxide storage catalytic converter and an SCR catalytic converter. A particulate filter is provided upstream of the nitrogen oxide storage catalytic converter or between the latter and the SCR catalytic converter or downstream of the SCR catalytic converter. The time of regeneration operating phases of the nitrogen oxide storage catalytic converter can be determined as a function of the nitrogen oxide content of the exhaust gas downstream of the nitrogen oxide storage catalytic converter or of the SCR catalytic converter and/or as a function of the ammonia loading of the latter. Moreover, a desired ammonia generation quantity can be determined for a respective regeneration operating phase. The installation and method are adopted for use for motor vehicle internal combustion engines and other engines which are operated predominantly in lean-burn mode.
1. An installation for aftertreatment of exhaust gas generated by a combustion device, said installation comprising the following components:
a nitrogen oxide storage catalytic converter configured for temporarily storing nitrogen oxides contained in the exhaust gas during adsorption operating phases with a lean exhaust gas air ratio, and releasing and reducing stored nitrogen oxides, during regeneration operating phases with a rich exhaust gas air ratio;
an SCR catalytic converter arranged downstream of the nitrogen oxide storage catalytic converter, said SCR catalytic converter being configured to receive and store ammonia generated by the nitrogen oxide storage catalytic converter, and to reduce nitrogen oxides in the exhaust gas with the stored ammonia;
a particulate filter arranged upstream of the SCR catalytic converter and downstream of the nitrogen oxide storage catalytic converter; and
a reducing agent supplying device coupled to feed reducing agent into the exhaust gas downstream of the combustion device and upstream of the nitrogen oxide storage catalytic converter such that during lean-burn operation of the combustion engine, an exhaust gas air ratio upstream of the nitrogen oxide storage catalytic converter is lowered into a rich range, for performing regeneration of the nitrogen oxide storage catalytic converter.
2. The installation according to claim 1 , further comprising a first oxidation catalytic converter arranged upstream of the nitrogen oxide storage catalytic converter.
3. The installation according to claim 1 , further comprising an NO 2 producing catalytic converter disposed upstream of the SCR catalytic converter.
4. The installation according to claim 3 , wherein said NO 2 producing catalytic converter includes a catalyst material which allows ammonia contained in the exhaust gas to pass through without a conversion reaction when the exhaust gas composition is rich.
5. The installation according to claim 2 , further comprising a second oxidation catalytic converter disposed at a downstream extremity of the installation.
6. The installation according to claim 1 , wherein said particulate filter has a catalytic coating.
7. The installation according to claim 1 , further comprising means for determining a nitrogen oxide content in the exhaust gas stream, downstream of at least one of said components which is selected from the group consisting of the nitrogen oxide storage catalytic converter and the SCR catalytic converter.
8. The installation according to claim 1 , further comprising means situated downstream of at least the nitrogen oxide storage catalytic converter, for determining an ammonia amount from the SCR catalytic converter loading or from the exhaust gas stream.
9. The installation according to claim 1 , further comprising a reducing agent supplying device configured to feed fuel into the exhaust gas stream, as a reducing agent.
10. The installation according to claim 9 , wherein said fuel is hydrogen.
11. An exhaust gas aftertreatment method for a combustion device, said method comprising:
operating the combustion device under lean-burn conditions;
temporarily storing nitrogen oxides contained in the exhaust gas in a nitrogen oxide storage catalytic converter during adsorption phases;
releasing stored nitrogen oxides from the nitrogen oxide storage catalytic converter during regeneration phases, and thereby generating ammonia;
temporarily storing generated ammonia;
using the stored ammonia for nitrogen oxide reduction in an SCR catalytic converter arranged downstream of the nitrogen oxide storage catalytic converter; and
during operation of said combustion device under lean burning conditions, lowering an exhaust gas air ratio upstream of the nitrogen oxide storage catalytic converter into the rich range, by feeding reducing agent being fed to the exhaust gas, for regeneration of the nitrogen oxide storage catalytic converter in a respective regeneration phase.
12. The method according to claim 11 , further comprising:
filtering out particulates contained in the exhaust gas leaving the nitrogen oxide storage catalytic converter; and
guiding filtered exhaust gas to SCR catalytic converter.
13. The method according to claim 11 , wherein the combustion device is operated within an air ratio between 1.0 and 1.2 in said regeneration phases.
14. The method according to claim 11 , further comprising enhancing an NO 2 -ratio of the nitrogen oxides in the exhaust gas by means of a catalytic oxidation with an NO 2 -producing catalytic converter.
15. The method according to claim 11 , wherein the lowering of said air ratio is based on a desired ammonia generation quantity.
16. The method according to claim 11 , further comprising:
adjusting a duration of a regeneration operation phase based on a desired ammonia generation quantity.
17. The method according to claim 11 , further comprising:
determining an exhaust air ratio downstream of the nitrogen oxide storage catalytic converter; and
terminating a regeneration operation phase if the determined exhaust air ratio drops below a threshold value.