Crosslinked polyvinyl acetals
View Patent ↗The invention relates to a method for producing crosslinked polyvinyl acetals, according to which a vinyl alcohol copolymer is reacted with at least one polyaldehyde and is partly esterified.
1. A process for the production of cross-linked polyvinyl acetals, wherein a polymer (A1) is cross-linked, and polymer (A1) contains, relative to its total weight,
a) 1.0 to 99.9% by weight of structural units of formula (1)
in which R 1 means hydrogen or methyl,
b) 0 to 99.0% by weight of structural units of formula (2)
in which R 2 represents hydrogen or an alkyl with 1 to 6 carbon atoms,
c) 0 to 70.0% by weight of structural units of formula (3)
in which R 3 , R 4 , R 5 and R 6 , in each case independently of one another, are each radicals with a molecular weight in the range of 1 to 500 g/mol,
d) 0.00001 to 30.0% by weight of structural units of formula (4)
in which R 7 and R 8 , in each case independently of one another, are hydrogen, carboxy, alkyl group with 1 to 10 carbon atoms which is optionally substituted by one or more COOH groups, or an optionally substituted aryl group with 6 to 12 carbon atoms,
said process comprising in any sequence:
(i) reacting polymer (A1) with at least one polyaldehyde of formula (5),
R 9 (CHO) n (5)
in which R 9 represents a bond or a radical having 1 to 40 carbon atoms, and n is an integer that is greater than or equal to 2, and
(ii) partially esterifying groups of formula (1) and formula (4) with one another.
2. A process according to claim 1 , wherein n is 2 or 3.
3. A process according to claim 1 , wherein R 9 is an aliphatic, cycloaliphatic and/or aromatic group with 1 to 12 carbon atoms.
4. A process according to claim 1 , wherein glutaric dialdehyde and/or n-nonanedial is used as compound of formula (5).
5. A process according to claim 1 , further comprising, at any time during the process, adding at least one compound of formula (6),
in which R 10 and R 11 , in each case independently of one another, are hydrogen, alkyl with 1 to 10 carbon atoms or an optionally substituted aryl group with 6 to 12 carbon atoms.
6. A process according to claim 5 , wherein said compound of formula (6) is n-butyraldehyde.
7. A process according to claim 5 , wherein the compounds of formulas 5 and 6 are used in the following ratio:
(1) 95.00 to 99.99 parts by weight of at least one compound of formula (6)
(2) 0.01 to 5.00 parts by weight of at least one polyaldehyde of formula (5).
8. A process according to claim 1 , wherein the esterification of (ii), optionally in the presence of at least one softener, is performed at a temperature in the range of 80 to 280° C.
9. A process according to claim 8 , wherein cross-linking is performed in an extruder, a kneading aggregate or another heatable aggregate.
10. A cross-linked polyvinyl acetal that can be obtained by a process according to claim 1 .
11. A cross-linked polyvinyl acetal according to claim 10 , wherein said cross-linked polyvinyl has a total content of esterified and non-esterified carboxyl groups of less than or equal to 10.0% by weight, relative to the total weight of the polyvinyl acetal.
12. A cross-linked polyvinyl acetal according to claim 10 , wherein said cross-linked polyvinyl acetal contains a softener.
13. A molding compound comprising a polyvinyl acetal according to claim 10 .
14. A film comprising a polyvinyl acetal according to claim 10 .
15. In a laminated safety glass article, the improvement wherein said article comprises a film according to claim 14 .
16. In a coating composition, the improvement wherein said coating composition comprises a polyvinyl acetal according to claim 10 .
17. In an electronic system having at least one ion-conductive intermediate layer, the improvement wherein a polyvinyl acetal according to claim 10 is used as an ion-conductive intermediate layer.