Switching element
View Patent ↗The present invention provides a switching element that has a stable bistable characteristic and a high transition voltage and demonstrates excellent cyclic performance. The switching element has two stable resistance values with respect to the voltage applied between electrodes, wherein a first electrode layer, an organic bistable material layer, and a second electrode layer are successively formed as thin films on a substrate and the organic bistable material constituting the organic bistable material layer is a quinomethane-based compound or a monoquinomethane-based compound. A metal constituting the second electrode layer is diffused into the organic bistable material layer. It is preferred that the second electrode layer be formed by vapor deposition and the temperature of the substrate during the vapor deposition be 30-150° C.
1. A switching element having two stable resistance values with respect to the voltage applied between electrodes, comprising:
a substrate,
a first electrode layer,
an organic bistable material layer, and
a second electrode layer, said first electrode layer, said organic bistable material layer and said second electrode being successively formed as thin films on said substrate
wherein the organic bistable material constituting said organic bistable material layer is a quinomethane-based compound represented by the general formula (I) below:
wherein each of R 1 -R 4 represents a group selected from a hydrogen atom, an optionally substituted C 1-6 alkyl group, and an optionally substituted aryl group, where R 1 -R 4 may be same or different, each of R 5 and R 6 represents an optionally substituted aryl group or an optionally substituted hetero ring, where R 5 , R 6 may be same or different and A represents a group selected from groups (1)-(10) shown below
2. The switching element of claim 1 , wherein said second electrode layer is formed by vapor deposition and the temperature of said substrate during said vapor deposition is 30-150° C.
3. The switching element of claim 1 , wherein said second electrode layer comprises at least one species selected from gold, platinum, rhodium, silver, and chromium.