Pyrogenic silicon dioxide powder and dispersion thereof
View Patent ↗Pyrogenically produced silicon dioxide powder with a specific surface area of between 5 and 600 m 2 /g and a carbon content of less than 500 ppm, which displays a specific dibutyl phthalate absorption of less than or equal to 1.2 g dibutyl phthalate/100 g SiO2 per m 2 of specific surface area and a specific thickening action of less than 15 mPas/m 2 of specific surface area. It is produced by supplying vaporous tetramethoxysilane and/or tetraethoxysilane together with air and separately hydrogen to a burner, and allowing the mixture of gases to react in a flame in a reaction chamber connected in series to the burner, and separating the solid reaction product from the gas stream by known means, the lambda value in the burner being between 0.95 and 1.5 and sufficient secondary air also being supplied to the reaction chamber that the lambda value in the reaction chamber is between 0.8 and 1.6. The invention also provides a dispersion containing the silicon dioxide powder and the use of the powder and of the dispersion.
1. A pyrogenically produced silicon dioxide powder having the following characteristics:
a specific surface area of between 5 and 600 m 2 /g;
a specific dibutyl phthalate absorption of less than or equal to 1.2 g dibutyl phthalate/100 g SiO 2 per m 2 of specific surface area;
and a specific thickening effect of less than 15 mPas per m 2 of specific surface area,
wherein said powder has a carbon content of less than 500 ppm and a chloride content of less than 20 ppm.
2. The pyrogenically produced silicon dioxide powder according to claim 1 , wherein a specific compacted bulk density is between 1000 and 10000 g/l ×m 2 of specific surface area.
3. A process for making the silicon dioxide powder according to claim 1 , comprising:
premixing and supplying vaporous tetramethoxysilane, tetraethoxysilane, or a combination thereof with air or with oxygen-enriched air to a burner present in a reaction chamber;
separately supplying hydrogen to said burner to form a mixture with said tetramethoxysilane, tetraethoxysilane, or combination thereof;
introducing secondary air to said reaction chamber;
reacting said mixture in a flame of said burner; and
separating solid reaction product from a gas stream,
wherein a lambda value in said burner is from 0.95 to 1.5, and a lambda value for said secondary air is from 0.8 to 1.6.
4. The process according to claim 3 , wherein a volume ratio of oxygen/hydrogen in the burner is between 0.2 and 2.8.
5. The process according to claim 3 , wherein a discharge velocity of the gases leaving the burner is at least 10 ms −1 .
6. An aqueous dispersion comprising water and the pyrogenically produced silicon dioxide powder according to claim 1 .
7. The aqueous dispersion according to claim 6 , wherein a content of silicon dioxide powder in the dispersion is between 20 and 80wt %.
8. The aqueous dispersion according to claim 6 , wherein an average aggregate diameter in the dispersion is less than 200 nm.
9. The aqueous dispersion according to claim 6 , wherein the aqueous dispersion further comprises an additive selected from the group consisting of an oxidizing agent, a per-acid, an oxidation activator, a corrosion inhibitor, or a surfactant.
10. The aqueous dispersion according to claim 9 , wherein said additive is hydrogen peroxide or benzotriazole.
11. A process for the production of the aqueous dispersion according to claim 6 , comprising:
incorporating said pyrogenically produced silicon dioxide powder with a dispersing device into water, and
stabilizing said aqueous dispersion by adding at least one of a base, a cationic polymer, an aluminium salt, a mixture of a cationic polymer and an aluminium salt, or an acid to form a stabilized aqueous dispersion.
12. The process according to claim 11 , wherein said stabilizing occurs in the presence of tetramethyl ammonium hydroxide or aluminium hydroxychloride in an acid medium.
13. The process according to claim 11 , further comprising dispersing said stabilized aqueous dispersion for a period of 5 to 30 minutes.
14. The process according to claim 11 , wherein said dispersing device is a rotor-stator system, a planetary compounder, or a high-energy mill.
15. The aqueous dispersion according to claim 6 , where a content of silicon dioxide powder in the dispersion is between 40 and 60 wt %.
16. A rubber, a silicone rubber, a plastic or a paper comprising the silicon dioxide powder according to claim 1 as a filler.
17. The pyrogenically produced silicon dioxide powder according to claim 1 , wherein the chloride content is less than 14 ppm.