Retarding oxidants for preparing conductive polymers
View Patent ↗Process for preparing specific oxidants which in mixtures with precursors for preparing conductive polymers display a long processing time during the polymerization; oxidants obtainable by this process; mixtures comprising such specific (retarding) oxidants and the use of said oxidants for preparing solid electrolyte capacitors and conductive layers.
1. A process for the oxidative polymerization of precursors for the preparation of conductive polymers, the process comprising:
providing a metal salt of an organic acid or an inorganic acid having organic radicals;
preparing an oxidant by contacting the metal salt with an ion exchanger;
mixing the oxidant with at least one conductive polymer precursor for preparing at least one conductive polymer; and
separating the ion exchanger from the oxidant before mixing the oxidant with the at least one conductive polymer precursor.
2. The process according to claim 1 , wherein the ion exchanger used is an anion exchanger.
3. The process according to claim 2 , wherein the ion exchanger used is a weakly basic anion exchanger.
4. The process according to claim 1 , wherein the metal salt is a transition metal salt.
5. The process according to claim 4 , wherein the transition metal salt is an iron(III) salt.
6. The process according to claim 5 , wherein the transition metal salt is Fe(III) p-toluenesulphonate, Fe(III) o-toluenesulphonate or a mixture of Fe(III) p-toluenesulphonate and Fe(III) o-toluenesulphonate.
7. The process according to claim 1 , wherein the radical of the organic acid is a radical of a sulphonic acid.
8. The process according to claim 1 , wherein the process is carried out in the presence of one or more solvent(s).
9. The Process according to claim 8 , wherein the solvent or solvents used is/are one or more alcohol(s), water or a mixture of one or more alcohol(s) and water.
10. The process according to claim 9 , wherein said alcohol(s) is/are butanol, ethanol or methanol.
11. The process according to claim 8 , wherein the oxidant is separated from the solvent after treatment with the ion exchanger and optionally is redissolved in the same solvent or another solvent.
12. The process according to claim 1 , wherein said oxidant is present in solution and the solution has a water content of from 0 to 10% by weight based on the total weight of the solution.
13. The process according to claim 1 , wherein the separation of the oxidant from the ion exchanger is accomplished by passing a solution of the metal salt through a column containing the ion exchanger, or bringing the metal salt, a solvent and the ion exchanger together in a vessel followed by separating of the ion exchanger from the oxidant.