Polyorganiosiloxane-containing graft copolymer, resin compositions containing the same and process for produciton of polyorganosiloxane emulsions
View Patent ↗The present invention relates to a flame retardant which is a graft copolymer. The graft copolymer is obtained by polymerizing a vinyl monomer containing at least two polymerizable groups, and at least one other vinyl monomer, in the presence of polyorganosiloxane particles in a latex state. The polyorganosiloxane particles contain grafting agents that are unevenly distributed on the surface thereof. The present invention also relates to thermoplastic resins containing this flame retardant.
1. A graft copolymer containing polyorganosiloxane obtained by polymerizing,
1 to 8 parts by weight of a vinyl monomer (B) comprising 100 to 20% by weight of a multi-functional monomer containing at least two polymerizable unsaturated bonds in a molecule (b-1) and 0 to 80% by weight of another copolymerizable monomer (b-2) and
5 to 70 parts by weight of a vinyl monomer (C),
in the presence of 30 to 95 parts by weight of polyorganosiloxane particles in a latex state (A), so that the total amount of polyorganosiloxane (A), vinyl monomer (B) and vinyl monomer (C) becomes 100 parts by weight,
wherein the polyorganosiloxane particles in a latex state (A) are prepared by polymerizing siloxane monomers in the presence of a silane grafting agent (E), thereby producing a modified polyorgansiloxane, and said modified polyorganosiloxane is subsequently reacted with a silane grafting agent (F) such that grafting agent (F) is unevenly distributed on the surface of the polyorgansiloxane particles.
2. The graft copolymer containing polyorganosiloxane of claim 1 , wherein polyorganosiloxane (A) is obtained by seed polymerizing organosiloxane using a seed polymer that is swelled by organosiloxane.
3. The graft copolymer containing polyorganosiloxane of claim 2 , wherein the particle size of said seed polymer is 0.001 to 0.03 μm.
4. The graft copolymer containing polyorganosiloxane of claim 2 , wherein Tg of said seed polymer is at most 0° C.
5. The graft copolymer containing polyorganosiloxane of claim 2 , wherein the proportion of said seed polymer to polyorganosiloxane (A) is 0.1 to 10% by weight.
6. The graft copolymer containing polyorganosiloxane of claim 2 , wherein the swelling volume ratio of said seed polymer is 3 to 50 times.
7. The graft copolymer containing polyorganosiloxane of claim 2 , wherein the swelling volume ratio of said seed polymer is 5 to 25 times.
8. The graft copolymer containing polyorganosiloxane of claim 1 , wherein vinyl monomer (C) is at least one monomer selected from the group consisting of an aromatic vinyl monomer, a cyanized vinyl monomer, a (meth)acrylic ester monomer and a vinyl monomer containing a carboxyl group.
9. The graft copolymer containing polyorganosiloxane of claim 1 , wherein a radical polymerization initiator (D) having solubility to water of 0.5 to 10 g/100 g (20° C.) and hydrogen drawing properties of 10 to 30% is used when polymerizing vinyl monomer (B) and/or vinyl monomer (C).
10. The graft copolymer containing polyorganosiloxane of claim 1 , wherein the amount of grafting agent (E) is 0.1 to 10 parts by weight based on 100 parts by weight of polyorganosiloxane (A).
11. The graft copolymer containing polyorganosiloxane of claim 1 , wherein the reaction temperature of grafting agent (F) and vinyl monomer (B) is 20 to 60° C.
12. A flame retardant comprising the graft copolymer containing polyorganosiloxane of claim 1 .
13. A resin composition comprising 0.1 to 20 parts by weight of the flame retardant of claim 12 based on 100 parts by weight of thermoplastic resin.