Apparatus and process for the production of vinyl chloride by thermal cracking of 1,2-dichloroethane
View Patent ↗The invention relates to a process for the production of vinyl chloride by thermal cracking, in which the energy balance, the operating time of the cracking furnace and/or the yield of the reaction are distinctly enhanced in comparison with the prior art. A pressure of from 1.4 to 2.5 MPa is established in the cracking coil at a temperature of from 450 to 550° C. and, for pre-heating the EDC (=1,2-dichloroethane) introduced, inter alia the waste heat of the gas stream leaving the top of the quench column is utilized.
1. A process for the production of vinyl chloride by thermal cracking of 1,2-dichloroethane in a cracking furnace, in which a medium pressure of from 1.4 to 2.5 MPa is maintained in the system and an externally heatable and separately regulatable first heat exchanger is provided by means of which pressure fluctuations and temperature fluctuations within the system can be compensated for, and wherein the EDC is introduced into the cracking furnace in gaseous form through an EDC feed line; and wherein a second heat exchanger is provided in the EDC feed line, wherein said second heat exchanger serves to heat the EDC that is to be introduced into the first heat exchanger.
2. A process according to claim 1 , wherein a second heat exchanger brings the EDC to 120-150° C.
3. A process according to claim 1 , wherein a third heat exchanger heats the EDC to 200-250° C.
4. A process according to claim 1 , wherein the pressure in the cracking coil in the radiation zone of the cracking furnace is from 1.6 to 2.2 MPa.
5. A process according to claim 1 , wherein the pressure in the cracking coil in the radiation zone of the cracking furnace is from 1.8 to 2.1 MPa.
6. A process according to claim 1 , wherein the temperature in the cracking coil in the radiation zone of the cracking furnace is from 450 to 550° C.
7. A process according to claim 1 , in which the EDC is heated in the cracking furnace to at least 450° C. within from 5 to 10 seconds.
8. A process according to claim 1 , in which the total residence time of the EDC in the radiation zone of the cracking furnace is from 15 to 30 seconds.
9. A process according to claim 1 , in which the energy supply to the cracking furnace is implemented in three burner row stages of which each stage may comprise one or more burners, the first burner row stage, at the EDC entry, providing from 30 to 70%, the second, middle burner row stage providing from 20 to 40% and the third burner row stage, at the exit of the cracking gases, providing from 10 to 20%.
10. A process according to claim 1 , in which the pressure in the quench column is from 1.4 to 2 MPa.