Polyolefin resin composition and combination of resin shaped bodies using same
There are provided a polyolefin-based resin composition that is substantially prevented from suffering from oxidative deterioration of polyolefin resin and stably used even when positioned in contact with or near to vinyl chloride-based resins, as well as a combination of a vinyl-chloride-based resin molded article and a molded article made of the polyolefin-based resin composition. The polyolefin-based resin composition used in contact with or near to vinyl chloride-based resins, comprises (A) 100 parts by mass of a polyolefin-based resin; and (B) 0.01 to 5 parts by mass of a phenol-based antioxidant containing no aliphatic ester group and/or a sulfur-based antioxidant containing no aliphatic ester group, and may further contain, if required, 0.01 to 3 parts by mass of a metal deactivator containing no aliphatic ester, and 50 to 250 parts by mass of a metal hydrate and/or a metal hydroxide. In the combination of the vinyl-chloride-based resin molded article and the polyolefin-based molded article, both the molded articles are positioned in contact with or near to each other, and the polyolefin-based molded article is made of the above polyolefin-based resin composition.
1 . A polyolefin-based resin composition used in contact with or near to vinyl chloride-based resins, comprising:
(A) 100 parts by mass of a polyolefin-based resin; and
(B) 0.01 to 5 parts by mass of a phenol-based antioxidant containing no aliphatic ester group and/or a sulfur-based antioxidant containing no aliphatic ester group.
2 . A combination of a vinyl chloride-based resin molded article and a polyolefin-based resin molded article that are positioned in contact with or near to each other, said polyolefin-based resin molded article being made of a polyolefin-based resin composition comprising:
(A) 100 parts by mass of a polyolefin-based resin; and
(B) 0.01 to 5 parts by mass of a phenol-based antioxidant containing no aliphatic ester group and/or a sulfur-based antioxidant containing no aliphatic ester group.
3 . The polyolefin-based resin composition according to claim 1 , further comprising (C) a metal deactivator containing no aliphatic ester in an amount of 0.01 to 5 parts by mass based on 100 parts by mass of the polyolefin-based resin.
4 . The polyolefin-based resin composition according to claim 1 , further comprising (D) a metal hydrate and/or a metal hydroxide in an amount of 50 to 250 parts by mass based on 100 parts by mass of the polyolefin-based resin.
5 . The polyolefin-based resin composition according to claim 1 , wherein said phenol-based antioxidant (B) is at least one compound selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) a compound represented by the general formula (I):
wherein X is a group represented by the general formula (II) with the proviso that the three X groups may be the same or different from each other:
wherein R1 and R4 are independently C 1 to C 8 alkyl and may be the same or different from each other; and R2, R3, R5 and R6 are independently hydrogen or C 1 to C 8 alkyl and may be the same or different from each other;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).
6 . The polyolefin-based resin composition according to claim 3 , wherein said metal deactivator (C) containing no aliphatic ester is 1,2-bis(3,5-di-t-butyl-4-hydroxyhydrocinnamoyl)hydrazine.
7 . The polyolefin-based resin composition according to claim 4 , wherein said metal hydrate and/or said metal hydroxide (D) are magnesium hydroxide and/or aluminum hydroxide.
8 . A polyolefin-based resin composition used in contact with or near to vinyl chloride-based resins, comprising 100 parts by mass of polypropylene; 0.01 to 3 parts by mass of 1,2-bis(3,5-di-t-butyl-4-hydroxyhydrocinnamoyl)hydrazine, and 0.01 to 5 parts by mass of at least one antioxidant selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) 1,1,3-tris{2-methyl-4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-5-t-butyl phenyl}butane;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).
9 . A polyolefin-based resin composition used in contact with or near to vinyl chloride-based resins, comprising 100 parts by mass of polypropylene; 50 to 250 parts by mass of magnesium hydroxide; and 0.01 to 5 parts by mass of at least one antioxidant selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) 1,1,3-tris{2-methyl-4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-5-t-butyl phenyl}butane;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).
10 . The combination according to claim 2 , wherein said vinyl chloride-based resin molded article is enclosed in said polyolefin-based resin molded article.
11 . The combination according to claim 2 , wherein said polyolefin-based resin molded article is enclosed in said vinyl chloride-based resin molded article.
12 . The combination according to claim 2 , wherein a layer made of said vinyl chloride-based resin molded article and a layer made of said polyolefin-based resin molded article are directly or indirectly laminated on each other.
13 . The combination according to claim 2 , wherein said polyolefin-based resin composition further comprises (C) a metal deactivator containing no aliphatic ester in an amount of 0.01 to 5 parts by mass based on 100 parts by mass of the polyolefin-based resin.
14 . The combination according to claim 2 , wherein said polyolefin-based resin composition further comprises (D) a metal hydrate and/or a metal hydroxide in an amount of 50 to 250 parts by mass based on 100 parts by mass of the polyolefin-based resin.
15 . The combination according to claim 2 , wherein said phenol-based antioxidant (B) is at least one compound selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) a compound represented by the general formula (I):
wherein X is a group represented by the general formula (II) with the proviso that the three X groups may be the same or different from each other:
wherein R1 and R4 are independently C 1 to C 8 alkyl and may be the same or different from each other; and R2, R3, R5 and R6 are independently hydrogen or C 1 to C 8 alkyl and may be the same or different from each other;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).
16 . The combination according to claim 13 , wherein said metal deactivator (C) containing no aliphatic ester is 1,2-bis(3,5-di-t-butyl-4-hydroxyhydrocinnamoyl)hydrazine.
17 . The combination according to claim 14 , wherein said metal hydrate and/or said metal hydroxide (D) are magnesium hydroxide and/or aluminum hydroxide.
18 . A combination of a vinyl chloride-based resin molded article and a polyolefin-based resin molded article that are positioned in contact with or near to each other, said polyolefin-based resin molded article being made of a polyolefin-based resin composition comprising 100 parts by mass of polypropylene; 0.01 to 3 parts by mass of 1,2-bis(3,5-di-t-butyl-4-hydroxyhydrocinnamoyl)hydrazine; and 0.01 to 5 parts by mass of at least one antioxidant selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) 1,1,3-tris{2-methyl-4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-5-t-butyl phenyl}butane;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).
19 . A combination of a vinyl chloride-based resin molded article and a polyolefin-based resin molded article that are positioned in contact with or near to each other, said polyolefin-based resin molded article being made of a polyolefin-based resin composition comprising 100 parts by mass of polypropylene; 50 to 250 parts by mass of magnesium hydroxide; and 0.01 to 5 parts by mass of at least one antioxidant selected from the group consisting of:
(i) 2,6-di-t-butyl-4-methyl phenol;
(ii) 1,1,3-tris{2-methyl-4-[3-(3,5-di-t-butyl-4-hydroxyphenyl)propionyloxy]-5-t-butyl phenyl}butane;
(iii) 1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene;
(iv) tris(3,5-di-t-butyl-4-hydroxybenzyl)isocyanurate; and
(v) 4,4′-butylidenebis-(3-methyl-6-t-butylphenol).