Method for producing rare earth based alloy powder and method for producing rare earth based sintered magnet
View Patent ↗An inventive method of making a rare-earth alloy powder is used to produce a rare-earth sintered magnet, whose main phase has a composition R 2 T 14 A (where R is one of the rare-earth elements including Y; T is Fe with or without a non-Fe transition metal; and A is boron with or without carbon). The method includes the steps of: preparing a first rare-earth rapidly solidified alloy, having a columnar texture with an average dendritic width within a first range, by subjecting a melt of a first rare-earth alloy with a first composition to a rapid cooling process; preparing a second rare-earth rapidly solidified alloy, having a columnar texture with an average dendritic width smaller than that of the first rare-earth rapidly solidified alloy and falling within a second range, by subjecting a melt of a second rare-earth alloy with a second composition to the rapid cooling process; making a first rare-earth alloy powder by pulverizing the first solidified alloy; making a second rare-earth alloy powder by pulverizing the second solidified alloy; and making a powder blend including the first and second rare-earth alloy powders.
1. A method of making a rare-earth alloy powder for use to produce a rare-earth sintered magnet, of which a main phase has a composition represented by R 2 T 14 A (where R is one of the rare-earth elements including Y; T is either Fe alone or a mixture of Fe and a transition metal element other than Fe; and A is either boron alone or a mixture of boron and carbon), the method comprising the steps of:
preparing a first R—Fe—B based rare-earth rapidly solidified alloy, which has a columnar texture with an average dendritic width falling within a first range, by subjecting a melt of a first R—Fe—B based rare-earth alloy with a first composition to a rapid cooling process;
preparing a second R—Fe—B based rare-earth rapidly solidified alloy, which has a columnar texture with an average dendritic width that is smaller than that of the first R—Fe—B based rare-earth rapidly solidified alloy and that falls within a second range, by subjecting a melt of a second R—Fe—B based rare-earth alloy with a second composition to the rapid cooling process;
making a first R—Fe—B based rare-earth alloy powder by pulverizing the first R—Fe—B based rare-earth rapidly solidified alloy;
making a second R—Fe—B based rare-earth alloy powder by pulverizing the second R—Fe—B based rare-earth rapidly solidified alloy; and
making a powder blend including the first and second R—Fe—B based rare-earth alloy powders.
2. The method of claim 1 , wherein the first range is equal to or greater than the mean particle size of the first R—Fe—B based rare-earth alloy powder, and the second range is less than the mean particle size of the second R—Fe—B based rare-earth alloy powder.
3. The method of claim 1 , wherein the first range is from 3 μm through 6 μm.
4. The method of claim 1 , wherein the second range is from 1.5 μm through 2.5 μm.
5. The method of claim 1 , comprising the steps of: obtaining a first rare-earth alloy coarse powder by coarsely pulverizing the first R—Fe—B based rare-earth rapidly solidified alloy; obtaining a second rare-earth alloy coarse powder by coarsely pulverizing the second R—Fe—B based rare-earth rapidly solidified alloy; making a blended coarse powder by blending the first and second rare-earth alloy coarse powders together; and obtaining the powder blend having a mean particle size of 1 μm to 10 μm by finely pulverizing the blended powder.
6. The method of claim 1 , comprising the steps of: making a first rare-earth powder having a mean particle size of 1 m to 10 μm from the first R—Fe—B based rare-earth rapidly solidified alloy; making a second rare-earth powder having a mean particle size of 1 μm to 10 μm from the second R—Fe—B based rare-earth rapidly solidified alloy; and obtaining the powder blend by blending the first and second rare-earth powders together.
7. The method of claim 1 , wherein the first and second R—Fe—B based rare-earth alloy powders included in the powder blend have a volume percentage ratio of 95:5 through 60:40.
8. The method of claim 1 , wherein the second R—Fe—B based rare-earth rapidly solidified alloy is made by a strip casting process.
9. The method of claim 1 , wherein the first R—Fe—B based rare-earth rapidly solidified alloy is made by a strip casting process.
10. The method of claim 1 , wherein the first R—Fe—B based rare-earth rapidly solidified alloy is made by a centrifugal casting process.
11. The method of claim 1 , wherein the first R—Fe—B based rare-earth rapidly solidified alloy includes 30 mass % to 32 mass % of R.
12. The method of claim 1 , wherein the second R—Fe—B based rare-earth rapidly solidified alloy includes 33.5 mass % to 35 mass % of R.
13. A method for producing a rare-earth sintered magnet, of which a main phase has a composition represented by R 2 T 14 A (where R is one of the rare-earth elements including Y; T is either Fe alone or a mixture of Fe and a transition metal element other than Fe; and A is either boron alone or a mixture of boron and carbon), the method comprising the steps of:
preparing a R—Fe—B based rare-earth alloy powder by the method of claim 1 ;
compacting a powder material, including the R—Fe—B based rare-earth alloy powder, thereby obtaining a compact; and
sintering the compact.
14. The method of claim 1 , wherein the first and second R—Fe—B based rare-earth rapidly solidified alloys have a structure consisting essentially of a dendrite texture alone and including substantially no chilled texture.