Synthesis of nanoparticles comprising metal (III) vanadate
View Patent ↗The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosophate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.
1. A composition comprising nanoparticles of metal (III) vanadate having only a polyol bound to the surface thereof, wherein said nanoparticles have a dimension of less than 30 nm.
2. The composition according to claim 1 , wherein the nanoparticles of metal (III) vanadate are doped.
3. The composition according to claim 1 , wherein said metal (III) is selected from elements of Group 13 of the Periodic Table, or bismuth, or the rare earth metals, optionally doped with one or a plurality of metals imparting luminescence and selected from lanthanides, indium, and bismuth.
4. The composition according to claim 1 , wherein said nanoparticles of metal (III) vanadate have a composition selected from the group consisting of BiVO 4 ; YVO 4 :Eu; YVO 4 :Bi; YVO 4 :Eu,Bi; YVO 4 doped with Tm, Tb, Ho, Er, Dy, Sm or In; GdVO 4 :Nd; and (Y 0.82 Al 0.07 La 0.06 ) VO 4 :Eu 0.05 .
5. The composition according to claim 1 wherein said at least one polyol has a molecular weight of not more than 200.
6. The composition according to claim 1 , wherein said nanoparticles of metal (III) vanadate have said diameter of less than 30 nm at a standard deviation from the mean of less than 30%.
7. The composition according to claim 1 , wherein the nanoparticles of metal (III) vanadate include a metal (III) vanadate/phosphate mixed crystal composition, which is optionally doped.
8. The composition according to claim 7 , wherein said metal (III) vanadate/phosphate mixed crystal composition is selected from BiV 1-x P x O 4 ; YV 1-x P x O 4 :EU; YV 1-x P x O 4 : Bi; YV 1-x P x O 4 :Eu,Bi; YV 1-x P x O 4 doped with Tm, Tb, Ho, Er, Dy, Sm or In; GdV 1-x O 4 :Eu; GdV 1-X P x O 4 :Bi; GdV 1-X P X O 4 :Eu,Bi; GdV 1-x P x O 4 ,Tm,Ho; GdV 1-x P x O 4 :Nd; or (Y 0.82 Al 0.07 La 0.06 ) V 1-x P x O 4 :Eu 0.05 , wherein 0<x<1.
9. The composition according to claim 7 , wherein the nanoparticles of metal (III) vanadate have the following formula:
Me(III)V 1-x P X O 4
wherein Me(III) is a trivalent metal atom and 0<x<1, wherein Me(III) can optionally be partially replaced with at least one doping metal atom.
10. The composition according to claim 9 , wherein x is 0.3 to 0.5.
11. A composition comprising nanoparticles of metal (III) vanadate having only a polyol bound to the surface thereof, wherein said nanoparticles have a dimension of less than 30 nm and are obtained by a method comprising reacting, in a reaction medium, a reactive vanadate source that is dissolvable or dispersible in the reaction medium and a reactive metal (III) salt that is dissolvable or dispersible in the reaction medium under heating conditions, wherein the reaction medium contains water and at least one polyol at a volume ratio of 20/80 to 90/10.
12. The composition according to claim 11 wherein said at least one polyol has a molecular weight of not more than 200.
13. A composition comprising nanoparticles of doped metal (III) vanadate having only a polyol bound to the surface thereof, wherein said nanoparticles have a dimension of less than 30 nm an increased quantum yield relative to equivalent nanoparticles of doped metal (III) vanadate that are devoid of at said polyol bound to the surface thereof.
14. The composition according to claim 13 wherein said at least one polyol has a molecular weight of not more than 200.
15. A composition comprising nanoparticles of metal (III) vanadate having only a polyol bound to the surface thereof, wherein said nanoparticles have a dimension of less than 30 nm and wherein said polyol has a molecular weight of less than 200.
16. A composition comprising nanoparticles of metal (III) vanadate having only a polyol bound to the surface thereof, wherein said nanoparticles have an average diameter of 1 to 25 nm at a standard deviation from the mean value of less than 30%.