Hot melt binder for asphalt product with reduced production temperature and applications of said binder
The binder is produced based on natural bitumen, or bitumen from the oil industry, and comprises a first additive which is constituted by a hydrocarbon wax whose melting point is greater than 85° C. This binder further comprises a fatty acid ester wax which is of synthetic, vegetable or fossil vegetable origin and which has a melting point of less than 85° C. Use in the production of sealing coatings for buildings or civil engineering works, coatings for traffic routes or urban amenities.
1. Asphalt product which can be hot-poured and which hardens by means of simple cooling, of the type comprising mineral fillers such as fines, sand and optionally gravel; and a thermofusible binder, this binder being based on natural bitumen or bitumen from the oil industry, of the type comprising, in addition to this base product, a first additive which is constituted by a hydrocarbon wax which is substantially insoluble in the base bitumen of the binder at ambient temperatures and whose melting point, measured in accordance with the standards ASTM D3945 and D3418, is between 110° C. and 140° C., and which reduces the production temperature of the asphalt product relative to that of the base product, characterised in that it further comprises a second additive which is constituted by a fatty acid ester wax selected from montanic acid esters or lignoceric acid esters, this wax having a melting point, measured in accordance with the above standards, of less than 85° C.,
wherein the binder contains from 4 to 15% by mass of the total formed by the first and second additives relative to the total mass of the binder, and
wherein the binder contains from 1 to 10% by mass of the second additive relative to the total mass of the binder.
2. Asphalt product according to claim 1 , characterised in that the penetrability of the base product is in the order of 35/50.
3. Asphalt product according to claim 1 , characterised in that the acid value of the fatty acid ester is between 10 and 70 mg KOH/g, in particular between 20 and 40 mg KOH/g.
4. Asphalt product according to claim 3 , characterised in that the acid value is substantially 28 mg KOH/g.
5. Asphalt product according to claim 1 , characterised in that the molecular weight of the fatty acid ester is between 500 and 3000 g/mol, in particular between 600 and 1000 g/mol.
6. Asphalt product according to claim 5 , characterised in that the molecular weight is substantially 816 g/mol.
7. Asphalt product according to claim 1 , characterised in that the hydrocarbon wax is a wax of polymethylene or polyolefine, in particular polyethylene, polypropylene or ethylene/propylene copolymer.
8. Asphalt product according to claim 1 , characterised in that the hydrocarbon wax has a penetration, measured at 25° C. in accordance with the standard ASTM D1321, of less than 15/10 mm.
9. Asphalt product according to claim 1 , characterised in that it further contains an elastomer, in particular a copolymer of styrene-butadiene-styrene, styrene-butadiene or styrene-isoprene-styrene.
10. Asphalt product according to claim 1 , characterised in that the penetrability of the base product, measured in accordance with the standard ASTM D1321, is between 25 and 35 tenths of a millimeter.
11. Asphalt product according to claim 1 , characterised in that the penetrability of the base product, measured in accordance with the standard ASTM D1321, is between 50 and 70 tenths of a millimeter.
12. Asphalt product according to claim 1 , characterised in that the fatty acid ester is constituted by a carboxylic monoacid ester having a linear chain.
13. Method for preparing an asphalt product which can be hot-poured and which hardens by means of simple cooling, comprising the following steps:
(a) a thermofusible binder is mixed with fillers, in particular mineral fillers, such as fines, sand and optionally gravel, this binder is based on natural bitumen or bitumen from the oil industry, of the type comprising, in addition to this base product, a first additive which is constituted by a hydrocarbon wax which is substantially insoluble in the base bitumen of the binder at ambient temperatures and whose melting point, measured in accordance with the standards ASTM D3945 and D3418, is between 110° C. and 140° C., and which reduces the production temperature of the asphalt product relative to that of the base product, characterised in that it further comprises a second additive which is constituted by a fatty acid ester wax selected from montanic acid esters or lignoceric acid esters, this wax having a melting point, measured in accordance with the above standards, of less than 85° C., the binder containing from 4 to 15% by mass of the total formed by the first and second additives relative to the total mass of the binder, and from 1 to 10% by mass of the second additive relative to the total mass of the binder,
(b) the mixture produced at step (a) is poured, and
(c) the poured mixture is allowed to cool,
the steps (a) and (b) being carried out at a temperature of between 150 and 170° C.
14. Bituminous concrete, of the type comprising mineral fillers such as fines, sand and optionally gravel; and a thermofusible binder, this binder being based on natural bitumen or bitumen from the oil industry, of the type comprising, in addition to this base product, a first additive which is constituted by a hydrocarbon wax which is substantially insoluble in the base bitumen of the binder at ambient temperatures and whose melting point, measured in accordance with the standards ASTM D3945 and D3418, is between 110° C. and 140° C., and which reduces the production temperature of the asphalt product relative to that of the base product, characterised in that it further comprises a second additive which is constituted by a fatty acid ester wax selected from montanic acid esters or lignoceric esters, this wax having a melting point, measured in accordance with the above standards, of less than 85° C.,
wherein the binder contains from 4 to 15% by mass of the total formed by the first and second additives relative to the total mass of the binder, and
wherein the binder contains from 1 to 10% by mass of the second additive relative to the total mass of the binder,
characterised in that it contains recovered asphalt which is recycled during production.
15. Asphalt product according to claim 1 , characterised in that it contains recovered asphalt which is recycled during production.
16. Bituminous concrete according to claim 14 , characterised in that the penetrability of the base product is in the order of 35/50.
17. Bituminous concrete according to claim 14 , characterised in that the acid value of the fatty acid ester is between 10 and 70 mg KOH/g, in particular between 20 and 40 mg KOH/g.
18. Bituminous concrete according to claim 17 , characterised in that the acid value is substantially 28 mg KOH/g.
19. Bituminous concrete according to claim 14 , characterised in that the molecular weight of the fatty acid ester is between 500 and 3000 g/mol, in particular between 600 and 1000 g/mol.
20. Bituminous concrete according to claim 19 , characterised in that the molecular weight is substantially 816 g/mol.
21. Bituminous concrete according to claim 14 , characterised in that the hydrocarbon wax is a wax of polymethylene or polyolefine, in particular polyethylene, polypropylene or ethylene/propylene copolymer.
22. Bituminous concrete according to claim 14 , characterised in that the hydrocarbon wax has a penetration, measured at 25° C. in accordance with the standard ASTM D1321, of less than 15/10 mm.
23. Bituminous concrete according to claim 14 , characterised in that it further contains an elastomer, in particular a copolymer of styrene-butadiene-styrene, styrene-butadiene or styrene-isoprene-styrene.
24. Bituminous concrete according to claim 14 , characterised in that the penetrability of the base product, measured in accordance with the standard ASTM D1321, is between 25 and 35 tenths of a millimeter.
25. Bituminous concrete according to claim 14 , characterised in that the penetrability of the base product, measured in accordance with the standard ASTM D1321, is between 50 and 70 tenths of a millimeters.
26. Bituminous concrete according to claim 14 , characterised in that the fatty acid ester is constituted by a carboxylic monoacid ester having a linear chain.