Phosphazene compound, photosensitive resin composition and use thereof
View Patent ↗Disclosed is a phosphazene compound and a photosensitive resin composition. The phosphazene compound is obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond and/or an isocyanate compound (C), wherein the phosphazene compound has an unsaturated double bond in its molecule. The photosensitive resin composition includes at least: a soluble polyimide resin (G-1) having a carboxyl group and/or a hydroxyl group and is soluble in an organic solvent, as the polyimide resins (G); and a phenoxyphosphazene compound (H-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (H-2), which is obtained by cross-linking the phenoxyphosphazene compound (H-1) and has at least one phenolic hydroxyl group, as the phosphazene compound (H), and the photosensitive resin composition further includes a (meth)acrylic compound (L).
1. A phosphazene compound, obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond, wherein the phosphazene compound has an unsaturated double bond and a phenolic hydroxyl group in its molecule; and
the epoxy compound (B) is at least one epoxy compound selected from the group consisting of glycidylmethacrylate, glycidylacrylate, allylglycidylether, glycidylvinylether, and a compound represented by the following formula (10)
wherein r represents an integer ranging from 0 to 40, and R 8 represents H or a methyl group.
2. The phosphazene compound as set forth in claim 1 , wherein the phenoxyphosphazene compound (A-1) is a circular phenoxyphosphazene compound (A-11) represented by formula (1)
where m represents an integer ranging from 3 to 25, and each of R 1 and R 2 represents a phenyl group or a hydroxyphenyl group, and a single molecule has one or more hydroxyphenyl groups.
3. A photosensitive resin composition, comprising at least the phosphazene compound as set forth in claim 1 and a soluble polyimide resin (D) which is soluble in an organic solvent.
4. The photosensitive resin composition as set forth in claim 3 , further comprising a photoreaction initiator (E-1).
5. A photosensitive resin composition, comprising at least the phosphazene compound as set forth in claim 1 and a photoreaction initiator (E-1).
6. The photosensitive resin composition as set forth in claim 3 , further comprising a compound having a carbon-carbon double bond (E-4).
7. The photosensitive resin composition as set forth in claim 3 , wherein 1 wt% or more of the soluble polyimide resin (D) is dissolved in at least one kind of an organic solvent selected from dioxolane, dioxane, tetrahydrofuran, N,N-dimethylformamide, N,N-dimethylacetamide, and N-methyl-2-pyrrolidone at temperature ranging from room temperature to 100° C.
8. A photosensitive resin film, being formed by using the photosensitive resin composition as set forth in claim 3 .
9. The photosensitive resin film as set forth in claim 8 , being used as a print wiring board adhesive sheet, a photosensitive cover lay film, a print wiring insulative protection film, or a print wiring board substrate.