IP Library Granted Patent US 7,232,856
Granted Patent B1
US 7,232,856 · App. 10/560,803 · Granted Jun 19, 2007

Flame-retardant polyolefin compounds and their use in surface coverings

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Quick Facts
Patent No.
US 7,232,856
App. No.
10/560,803
Granted
Jun 19, 2007
Kind
B1
Abstract

A flame-retardant compound is disclosed, comprising a polyolefin alloy and a combination of flame-retardant agents. The polyolefin alloy comprises at least one polyolefin and a metallocene-catalyzed olefin copolymer. The flame-retardant agents comprise a nanoclay and at least one inorganic flame-retardant. An essentially halogen-free flame-retardant compound is preferred. Surface coverings for mammalian-occupied spaces benefit from the properties of the flame-retardant compound.

Claims (36)

1. A flame-retardant compound, comprising:

(a) a polyolefin alloy of two different types of polyolefins; and

(b) a combination of flame-retardant agents,

wherein one type of polyolefin comprises two polyethylene polyolefins and ethylene-vinyl acetate and

wherein the other type of polyolefin is an elastomeric olefin copolymer to modify the modulus of the first type of polyolefin wherein the copolymer comprises ethylene monomer and a second olefin monomer comprises octene monomer,

wherein the flame-retardant agents comprise an intercalated nanoclay and at least one inorganic flame-retardant, and

wherein one inorganic flame-retardant is a hydroxide present in the compound of at least 65 parts by weight, per 100 parts by weight of polyolefin alloy.

2. The compound of claim 1 , wherein there are at least two types of inorganic flame-retardants, and wherein one is a borate and another is a hydroxide.

3. The compound of claim 2 , wherein the hydroxide comprises magnesium hydroxide and aluminum hydroxide.

4. The compound of claim 1 , wherein the elastomeric olefin copolymer is an olefin copolymer comprising from 2 to 20 weight percent of the total compound.

5. The compound of claim 1 , further comprising additives selected from the group consisting of fillers, antioxidants, stabilizer, lubricants, pigments, biocides, and combinations thereof.

6. The compound of claim 1 , wherein the compound is essentially halogen-free.

7. A biocidal, essentially halogen-free flame-retardant compound, comprising:

(a) an essentially halogen-free polyolefin alloy of two different types of polyolefins;

wherein one type of polyolefin comprises two polyethylene polyolefins and ethylene-vinyl acetate and

wherein the other type of polyolefin is an elastomeric olefin copolymer to modify the modulus of the first type of polyolefin wherein the copolymer comprises ethylene monomer and a second olefin monomer comprises octene monomer;

(b) an essentially halogen-free flame retardant including an intercalated nanoclay; and

(c) a biocide consisting essentially of barium metaborate.

8. The compound of claim 7 ,

wherein the flame-retardant agents comprise an intercalated nanoclay and at least one inorganic flame-retardant.

9. The compound of claim 8 , wherein there are at least two types of inorganic flame-retardants, and wherein one is a borate and another is a hydroxide.

10. The compound of claim 9 , wherein the hydroxide comprises magnesium hydroxide and aluminum hydroxide, and wherein the hydroxide is present in the compound of at least 65 parts by weight, per 100 parts by weight of polyolefin alloy.

11. The compound of claim 7 , further comprising additives selected from the group consisting of fillers, antioxidants, stabilizer, lubricants, pigments, and combinations thereof.

12. An article made from a compound according to claim 1 , wherein the compound is in the form of a film, a fiber, or a profile.

13. The article according to claim 12 , wherein the article is a surface covering comprising the film attached to a water-based adhesive.

14. The article according to claim 12 , wherein the article is a surface covering laminate comprising a film as a top layer and a reinforcing backing as the bottom layer and wherein the reinforcing backing is attached to an adhesive.

15. A mammalian-occupied space having surfaces having a surface covering comprising:

a film attached to a water-based adhesive,

wherein the film comprises:

(a) a polyolefin alloy of two different types of polyolefins; and

(b) a combination of flame-retardant agents,

wherein one type of polyolefin comprises two polyethylene polyolefins and ethylene-vinyl acetate and

wherein the other type of polyolefin is an elastomeric olefin copolymer to modify the modulus of the first type of polyolefin wherein the copolymer comprises ethylene monomer and a second olefin monomer having from 3 to 18 carbon atoms, and

wherein the flame-retardant agents comprise an intercalated nanoclay and at least one inorganic flame-retardant,

wherein one inorganic flame-retardant is a hydroxide present in the compound of at least 65 parts by weight, per 100 parts by weight of polyolefin alloy, and

wherein the surface covering passes ASTM E84-01 flame test when using a glass-reinforced concrete board substrate.

Assignments (8)
RELEASE OF SECURITY INTERESTS IN PATENTS RECORDED AT REEL 027522, FRAME 0154. Recorded Jun 24, 2025
From: WELLS FARGO CAPITAL FINANCE, LLC, AS ADMINISTRATIVE AGENT
To: AVIENT CORPORATION (F/K/A POLYONE CORPORATION); GSDI SPECIALTY DISPERSIONS, INC. (F/K/A GAYSON SILICON DISPERSIONS, INC.); THE COLORMATRIX CORPORATION; COLORMATRIX HOLDINGS, INC.
Reel/Frame 071711/0354 →
SECURITY AGREEMENT Recorded Nov 19, 2015
From: POLYONE CORPORATION; COLORMATRIX GROUP, INC.; COLORMATRIX HOLDINGS, INC.; THE COLORMATRIX CORPORATION; GAYSON SILICONE DISPERSIONS, INC.; POLYONE DESIGNED STRUCTURES AND SOLUTIONS LLC
To: CITIBANK, N.A,, AS ADMINISTRATIVE AGENT
Reel/Frame 037146/0724 →
RELEASE (REEL 027456 / FRAME 0779) Recorded Nov 18, 2015
From: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
To: POLYONE CORPORATION
Reel/Frame 037129/0199 →
RELEASE OF SECURITY INTEREST RECORDED AT REEL 027450 FRAME 0907 Recorded Feb 28, 2013
From: BANK OF AMERICA, N.A., AS AGENT
To: POLYONE CORPORATION
Reel/Frame 029900/0240 →
SECURITY AGREEMENT Recorded Dec 29, 2011
From: POLYONE CORPORATION
To: THE BANK OF NEW YORK MELLON TRUST COMPANY, N.A.
Reel/Frame 027456/0779 →
SECURITY AGREEMENT Recorded Dec 28, 2011
From: POLYONE CORPORATION
To: BANK OF AMERICA, N.A.
Reel/Frame 027450/0907 →
SECURITY AGREEMENT Recorded Dec 23, 2011
From: POLYONE CORPORATION; GAYSON SILICONE DISPERSIONS, INC.; COLORMATRIX CORPORATION, THE; COLORMATRIX HOLDINGS, INC.
To: WELLS FARGO CAPITAL FINANCE, LLC
Reel/Frame 027522/0154 →
RELEASE OF SECURITY INTEREST Recorded Sep 23, 2011
From: U.S. BANK TRUST NATIONAL ASSOCIATION; CROWLEY, INDIVIDUAL TRUSTEE, SUCCESSOR TO ANGELITA PENA, C/O US BANK TRUST NATIONAL ASSOCIATION, PATRICK J.
To: POLYONE CORPORATION
Reel/Frame 026961/0468 →