Ion-conductive thermoplastic compositions for electrochromic glazing
View Patent ↗The invention relates to ion-conductive thermoplastic compositions consisting of a partially acetalated polyvinyl alcohol, at least one support electrolyte and at least one softener, the partially acetalated polyvinyl alcohol containing two different acetal units. The invention also relates to electrochromic laminated glass systems produced using the ion-conductive compositions and to a method for producing said systems.
1. An ion-conductive thermoplastic composition comprising:
a partially acetalated polyvinyl alcohol,
0.1 to 25% by weight of at least one support electrolyte,
and at least one plasticizer,
wherein the partially acetalated polyvinyl alcohol comprises a co-polymer containing:
77.5% by weight polyvinyl butyral,
20.2% by weight polyvinyl alcohol,
1.8% by weight polyvinyl acetate, and
0.5% by weight acetal of glyoxylic acid.
2. The ion-conductive thermoplastic composition according to claim 1 , wherein the plasticizer comprises tetraethylene glycol dimethyl ether, and the support electrolyte comprises lithium trifluoromethane sulphonate.
3. The ion-conductive thermoplastic composition according to claim 2 , wherein the composition comprises 65% by weight of the partially acetalated polyvinyl alcohol copolymer and 35% by weight of the plasticizer and support electrolyte, with 7.33% by weight being the support electrolyte.
4. The ion-conductive thermoplastic composition according to claim 1 , further comprising a UV absorber.
5. The ion-conductive thermoplastic composition according to claim 1 , wherein the composition is in the form of a foil.