Alkoxylated dendrimers and use thereof as biodegradable demulsifiers
View Patent ↗Disclosed is the use of alkoxylated dendrimers for breaking oil/water emulsions. The alkoxylated dendrimers have a molecular weight of from 2400 to 100 000 g/mol and have been alkoxylated with C 2 -C 4 -alkylene oxide groups or a mixture of such alkylene oxide groups such that the alkoxylated dendrimer has a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group. The alkoxylated dendrimers are added to the oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified.
1. A method for demulsifying an oil/water emulsion, said method comprising adding an alkoxylated dendrimer to said oil/water emulsion in an amount from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified, said alkoxylated dendrimer being a dendritic polyester having a molecular weight of from 2400 to 100 000 g/mol, the molecular weight determined by GPC using polyethylene as standard, said dendritic polyester being alkoxylated with C 2 -C 4 -alkylene oxide groups or a mixture of C 2 -C 4 -alkylene oxide groups to provide the alkoxylated dendrimer with an average degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group, wherein the dendritic polyester has a starting alcohol and a dendritic growth component, said starting alcohol is selected from the group consisting of a mono-alcohol, di-alcohol, and polyfunctional alcohol, and the dendritic growth component is a carboxylic acid which has at least two hydroxyl groups.
2. The method of claim 1 , where the starting alcohol is selected from the group consisting of bis(trimethylolpropane), bis(trimethylolethane), dipentaerythritol, pentaerythritol, alkoxylated pentaerythritol, trimethylolethane, trimethylolpropane, alkoxylated trimethylolpropane, glycerol, diglycerol, triglycerol, polyglycerol, neopentyl glycol, dimethylolpropane, sorbitol, and mannitol.
3. The method of claim 1 , where the carboxylic acid is selected from the group consisting of dimethylolpropanoic acid, α,α-bis(hydroxymethyl)butanoic acid, α,α, α-tris(hydroxymethyl)ethanoic acid, α, α-bis(hydroxymethyl)pentanoic acid, α,α-bis(hydroxy)propanoic acid, and 3 5-dihydroxybenzoic acid.
4. The method of claim 1 , wherein the molecular weight of the alkoxylated dendrimer is from 10 000 to 50 000 g/mol.
5. The method of claim 1 , in which the average degree of alkoxylation is between 1 and 70 alkylene oxide units per free OH group.
6. The method of claim 1 , in which the C 2 -C 4 -alkylene oxide is ethylene oxide or propylene oxide or a mixture thereof.
7. The method of claim 1 , in which the mixture of C 2 -C 4 -alkylene oxide groups is a mixture of ethylene oxide and propylene oxide with a ratio from 1:2 to 1:10.
8. The method of claim 1 , where the alkoxylated dendrimer is crosslinked with a crosslinker selected from the group consisting of bisphenol A diglycidyl ether, butane-1,4-diol diglycidyl ether, hexane-1,6-diol diglycidyl ether, ethylene glycol diglycidyl ether, cyclohexanedimethanol diglycidyl ether, resorcinol diglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, glycerol propoxylate triglycidyl ether, polyglycerol polyglycidyl ether, p-aminophenol triglycidyl ether, polypropylene glycol diglycidyl ether, pentaerythritol tetraglycidyl ether, sorbitol polyglycidyl ether, trimethylolpropane trigiycidyl ether, castor oil triglycidyl ether, diaminobiphenyl tetraglycidyl ether, soya oil epoxide, adipic acid, maleic acid, phthalic acid, maleic anhydride, succinic anhydride, dodecylsuccinic anhydride, phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, dimethoxydimethylsilane, diethoxydimethylsilane, toluene diisocyanate, and diphenylmethane diisocyanate.