Method for desolvation of polymer solution
View Patent ↗An objective of the present invention is to provide a desolvation method for removing a solvent efficiently from a polymer solution. In the present desolvation method where the solvent is removed from the polymer solution by steam stripping using an apparatus comprising a pipe which connects a gas phase portion of a desolvation tank at the downstream and a liquid phase portion of a desolvation tank at the upstream, and an opening-degree adjusting mean (for example, pressure adjusting valve) fixed to this pipe, pressures are controlled such that a pressure difference (ΔP=P 2 −P 1 ) between pressures of each gas phase portion of desolvation tanks at the downstream and at the upstream is allowed to be larger by from 0.005 to 0.6 MPa, preferably from 0.05 to 0.3 MPa than a pressure difference when the opening-degree adjusting mean is fully opened. In addition, in another present invention, pressures are controlled such that the pressure difference between pressures of each gas phase portion of desolvation tanks at the downstream and at the upstream is allowed to be 0.036 MPa or larger, preferably 0.1 MPa or larger.
1. A method of desolvating a polymer solution, comprising:
(a) steam stripping solvent from a polymer solution in an upstream desolvation tank;
(b) steam stripping solvent from the polymer solution in a downstream desolvation tank
wherein
the upstream desolvation tank has a liquid phase portion and a gas phase portion,
downstream desolvation tank has a liquid phase portion and a gas phase portion,
the liquid phase portion of the upstream desolvation tank and the gas phase portion of the downstream desolvation tank are connected by a pipe, and
at least one opening-degree adjusting mean is fixed to the pipe; and
(c) controlling pressures such that a pressure difference (ΔP=P2−P1) between pressure (P2) of the gas phase portion of the downstream desolvation tank and pressure (P1) of the gas phase portion of the upstream desolvation tank is larger by from 0.005 to 0.6 MPa than a pressure difference (ΔP0=P20−P10) between pressure (P 20 ) of the gas phase portion of the downstream desolvation tank and a pressure (P10) of the gas phase portion of the upstream desolvation tank when the opening-degree adjusting mean is fully opened.
2. The method of claim 1 , wherein the pressure of the gas phase portion of the downstream desolvation tank is in the range from 0.02 to 1 MPaG.
3. The method of claim 2 , wherein the temperature of the liquid phase portion of the downstream desolvation tank is in the range from 100° C. to 200° C.
4. The method of claim 3 , wherein the solvent comprises at least one member selected from the group consisting of cyclohexane, cyclopentane, cycloheptane, toluene, benzene, xylene, n-hexane, n-pentane, isopentane, n-heptane, n-octane, n-decane and dichloromethane.
5. The method of claim 4 , wherein the polymer contained in the polymer solution is butadiene rubber, isoprene rubber, styrene-butadiene rubber, styrene• isoprene rubber, ethylene• α-olefin copolymer rubber, ethylene• α-olefin• non-conjugated diene copolymer rubber, butyl rubber, styrene• butadiene• styrene block copolymer, hydrogenated styrene• butadiene• styrene block copolymer, butadiene resin or acrylic resin.
6. The method of claim 1 , wherein the temperature of the liquid phase portion of the downstream desolvation tank is in the range from 100° C. to 200° C.
7. The method of claim 1 , wherein the opening-degree adjusting mean is a pressure adjusting valve or an orifice plate.
8. The method of claim 1 , wherein the concentration of the solvent remaining in a solvent-containing polymer to be loaded in the downstream desolvation tank is 10% by mass or less.
9. The method of claim 1 , wherein the polymer solution is continuously supplied and polymer contained in the polymer solution is continuously recovered.
10. The method of claim 1 , wherein the polymer contained in the polymer solution is butadiene rubber, isoprene rubber, styrene-butadiene rubber, styrene• isoprene rubber, ethylene• α-olefin copolymer rubber, ethylene• α-olefin• non-conjugated diene copolymer rubber, butyl rubber, styrene• butadiene• styrene block copolymer, hydrogenated styrene• butadiene• styrene block copolymer, butadiene resin or acrylic resin.
11. The method of claim 1 , wherein the solvent is at least one member selected from the group consisting of cyclohexane, cyclopentane, cycloheptane, toluene, benzene, xylene, n-hexane, n-pentane, isopentane, n-heptane, n-octane, n-decane and dichloromethane.
12. A method of desolvating a polymer solution, comprising:
(a) steam stripping solvent from a polymer solution in an upstream desolvation tank;
(b) steam stripping solvent from the polymer solution in a downstream desolvation tank
wherein
the upstream desolvation tank has a liquid phase portion and a gas phase portion,
downstream desolvation tank has a liquid phase portion and a gas phase portion,
the liquid phase portion of the upstream desolvation tank and the gas phase portion of the downstream desolvation tank are connected by a pipe, and
at least one opening-degree adjusting mean is fixed to the pipe; and
(c) controlling pressures such that a pressure difference (ΔP=P2−P1) between pressure (P2) of the gas phase portion of the downstream desolvation tank and pressure (P1) of the gas phase portion of the upstream desolvation tank is 0.036 MPa or larger.
13. The method of claim 12 , wherein the pressure of the gas phase portion of the downstream desolvation tank is in the range from 0.02 to 1 MPaG.
14. The method of claim 13 , wherein the temperature of the liquid phase portion of the downstream desolvation tank is in the range from 100° C. to 200° C.
15. The method of claim 14 , wherein the solvent is at least one member selected from the group consisting of cyclohexane, cyclopentane, cycloheptane, toluene, benzene, xylene, n-hexane, n-pentane, isopentane, n-heptane, n-octane, n-decane and dichloromethane.
16. The method of claim 15 , wherein the polymer contained in the polymer solution is butadiene rubber, isoprene rubber, styrene-butadiene rubber, styrene• isoprene rubber, ethylene• α-olefin copolymer rubber, ethylene• α-olefin• non-conjugated diene copolymer rubber, butyl rubber, styrene• butadiene• styrene block copolymer, hydrogenated styrene• butadiene• styrene block copolymer, butadiene resin or acrylic resin.
17. The method of claim 12 , wherein the temperature of the liquid phase portion of the downstream desolvation tank is in the range from 100° C. to 200° C.
18. The method of claim 12 , wherein the opening-degree adjusting mean is a pressure adjusting valve or an orifice plate.
19. The method of claim 12 , wherein the concentration of the solvent remaining in a solvent-containing polymer to be loaded in the downstream desolvation tank is 10% by mass or less.
20. The method of claim 12 , wherein the polymer solution is continuously supplied and polymer contained in the polymer solution is continuously recovered.
21. The method of claim 12 , wherein polymer contained in said polymer solution is butadiene rubber, isoprene rubber, styrene-butadiene rubber, styrene•isoprene rubber, ethylene•α-olefin copolymer rubber, ethylene•α-olefin•non-conjugated diene copolymer rubber, butyl rubber, styrene•butadiene•styrene block copolymer, hydrogenated styrene•butadiene• styrene block copolymer, butadiene resin or acrylic resin.
22. The method of claim 12 , wherein the solvent is at least one member selected from the group consisting of cyclohexane, cyclopentane, cycloheptane, toluene, benzene, xylene, n-hexane, n-pentane, isopentane, n-heptane, n-octane, n-decane and dichloromethane.