IP Library Granted Patent US 7,211,682
Granted Patent B2
US 7,211,682 · App. 10/563,762 · Granted May 1, 2007

Aqueous solution of a sodium salt of HEDTA

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Quick Facts
Patent No.
US 7,211,682
App. No.
10/563,762
Granted
May 1, 2007
Kind
B2
Abstract

The invention pertains to an aqueous solution of a sodium salt xNa + yH + of the chelating compound of formula I: wherein x=2.1–2.7, y=0.9–0.3, and x+y=3. The invention further pertains to a container comprising at least 0.5 kg of said aqueous solution and to a method of preparing an aqueous solution comprising at least 45 wt % of the sodium salt xNa + yH + of the chelating compound of formula I from Na 3 -HEDTA, comprising the steps of electrodialysing an aqueous solution containing less than 42 wt % of Na 3 -HEDTA using a bipolar membrane, thereby converting the trisodium salt solution to the solution of the sodium salt of formula I with x=2.1–2.7, y=0.9–0.3, and x+y=3.

Claims (9)

1. An aqueous solution comprising a sodium salt xNa + yH + of the chelating compound of formula I:

wherein x=2.1–2.7, y=0.9–0.3, and x+y=3.

2. The aqueous solution according to claim 1 comprising at least 45 wt % of the sodium salt xNa + yH + of the chelating compound of formula I wherein x=2.1–2.7, y=0.9–0.3, and x+y=3.

3. A container comprising at least 0.5 kg of an aqueous solution according to claim 1 .

4. A method for preparing an iron-chelate complex, comprising: contacting the aqueous solution according to claim 1 with an iron-containing material.

5. A method of preparing an aqueous solution comprising at least 45 wt % of the sodium salt xNa + yH + of the chelating compound of formula I according to claim 1 wherein x=2.1–2.7, y=0.9–0.3, and x+y=3 from the trisodium salt of N-(2-hydroxyethyl)ethylene-diamine-N,N′,N′-triacetic acid (Na 3 -HEDTA), comprising the step of electrodialysing at 20° C. an aqueous solution containing at least 42 wt % of Na 3 -HEDTA, or at a different temperature at maximally the concentration whereby the viscosity is the same or lower than the viscosity of 42 wt % Na 3 -HEDTA solution at 20° C., using a bipolar and a cation membrane, thereby converting the Na 3 -HEDTA solution to the solution of the sodium salt xNa + yH + of the chelating compound of formula I according to claim 1 wherein x=2.1–2.7, y=0.9–0.3, and x+y=3.

6. The method according to claim 5 wherein a caustic electrolyte is used.

7. A container comprising at least 0.5 kg of an aqueous solution according to claim 2 .

8. A method for preparing an iron-chelate complex, comprising: contacting the aqueous solution according to claim 2 with an iron-containing material.

Assignments (4)
CHANGE OF NAME Recorded Sep 18, 2019
From: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
To: NOURYON CHEMICALS INTERNATIONAL B.V.
Reel/Frame 050426/0671 →
SECURITY INTEREST Recorded Oct 1, 2018
From: STARFRUIT US MERGER SUB 1 LLC; STARFRUIT US MERGER SUB 2 LLC; AKZO NOBEL SURFACE CHEMISTRY LLC; AKZO NOBEL CHEMICALS B.V.; AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
To: WILMINGTON TRUST (LONDON) LIMITED, AS COLLATERAL AGENT
Reel/Frame 047231/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 13, 2017
From: AKZO NOBEL N.V.
To: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
Reel/Frame 044427/0759 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2006
From: HEUS, MARTIN; LAMMERS, HANS; LEPAGE, JIM
To: AKZO NOBEL N.V.
Reel/Frame 017298/0896 →