Electrochemical cell
View Patent ↗The invention describes an electrochemical cell for the electrolysis of an aqueous solution of hydrogen chloride, comprising at least an anode half-cell with an anode, a cathode half-cell with a gas diffusion electrode as cathode and an ion exchange membrane arranged between the anode half-cell and the cathode half-cell, the membrane consisting of at least a perfluorosulfonic acid polymer, wherein the gas diffusion electrode and the ion exchange membrane are adjacent to each other, characterised in that the gas diffusion electrode and the ion exchange membrane, under a pressure of 250 g/cm 2 and at a temperature of 60° C., have a contact area of at least 50%, with respect to the geometric area.
1. An electrochemical cell for electrolysis of an aqueous solution of hydrogen chloride comprising:
a) an anode half-cell comprising an anode,
b) a cathode half-cell comprising a gas diffusion electrode as the cathode, and
c) an ion exchange membrane comprising a perfluorosulfonic acid polymer which is positioned between a) and b)
wherein the gas diffusion electrode has a surface having a geometric area, and wherein the ion exchange membrane has a surface having a geometric area, the surface of the ion exchange membrane comprising a layer of the perfluorosulfonic acid polymer with a support member embedded therein, and wherein the surface of the gas diffusion electrode and the surface of the ion exchange membrane are adjacent to each other and, at a pressure of 250 g/cm 2 and a temperature of 60° C., the gas diffusion electrode and the ion exchange membrane have a contact area of at least 50% of their geometric area.
2. The electrochemical cell of claim 1 in which the contact area of the gas diffusion electrode and ion exchange membrane is at least 70%.
3. The electrochemical cell of claim 2 in which the ion exchange membrane comprises at least two layers of perfluorosulfonic acid polymer and a support member is embedded between the two layers or in at least one of the layers.
4. The electrochemical cell of claim 3 in which the two layers of perfluorosulfonic acid polymer have different equivalent weights.
5. The electrochemical cell of claim 2 in which the perfluorosulfonic acid polymer has an equivalent weight of from 600 to 2500.
6. The electrochemical cell of claim 1 in which the ion exchange membrane comprises at least two layers of perfluorosulfonic acid polymer and a support member is embedded between the two layers or in at least one of the layers.
7. The electrochemical cell of claim 6 in which the two layers of perfluorosulfonic acid polymer have different equivalent weights.
8. The electrochemical cell of claim 6 in which the perfluorosulfonic acid layer with one of its surfaces facing the gas diffusion electrode has a higher equivalent weight than any other perfluorosulfonic acid layer.
9. The electrochemical cell of claim 1 in which the perfluorosulfonic acid polymer has an equivalent weight of from 600 to 2500.
10. The electrochemical cell of claim 1 in which the perfluorosulfonic acid polymer has an equivalent weight of from 900 to 2000.
11. The electrochemical cell of claim 1 in which a catalyst layer for the gas diffusion electrode is applied to the ion exchange membrane.
12. The electrochemical cell of claim 1 , wherein the support member comprises gauze, woven fabric, braided fabric, knit fabric, non-woven material, plastic foam or elastically deformable material.
13. The electrochemical cell of claim 1 , wherein the support member comprises metal, plastic, carbon fibers or glass fibers.