Non-aqueous electrolyte battery
View Patent ↗A non-aqueous battery with improved volume energy density and enhanced load characteristics is made available even when using olivine-type lithium phosphate as a positive electrode active material. The non-aqueous electrolyte battery of the present invention is provided with a positive electrode ( 1 ) containing lithium iron phosphate as a positive electrode active material, a negative electrode ( 2 ), and a non-aqueous electrolyte ( 4 ). In the positive electrode ( 1 ), a positive electrode active material-containing layer that is made of the positive electrode active material, a conductive agent, and a binder agent is formed on a positive electrode current collector. The positive electrode current collector has a thickness of less than 20 μm and its surface that is in contact with the positive electrode active material-containing layer has a mean surface roughness Ra of greater than 0.026.
1. A non-aqueous electrolyte battery comprising:
a positive electrode comprising a positive electrode current collector and a positive electrode active material-containing layer formed on the positive electrode current collector,
a negative electrode, and
a non-aqueous electrolyte,
wherein the positive electrode active material-containing layer comprises:
particles of an olivine-type lithium phosphate as a positive electrode active material, and
first carbon particles having BET specific surface area of 70 m 2 /g or greater;
wherein the positive electrode current collector has a thickness of less than 20 μm, and a surface of the positive electrode current collector that is in contact with the positive electrode active material-containing layer has a mean surface roughness Ra of greater than 0.026 μm and smaller than 0.14 μm; and
wherein the positive electrode active material-containing layer has a filling density of 1.7 g/cm 3 or greater.
2. The non-aqueous electrolyte battery according to claim 1 , wherein the olivine-type lithium phosphate is lithium iron phosphate.
3. The non-aqueous electrolyte battery according to claim 2 ,
wherein the positive electrode current collector is an aluminum foil subjected to a roughened process.
4. The non-aqueous electrolyte battery according to claim 3 , wherein the roughening process is carried out by polishing by blasting.
5. The non-aqueous electrolyte battery according to claim 2 , wherein the lithium iron phosphate particles have an average particle size of 10 μm or less.
6. The non-aqueous electrolyte battery according to claim 2 , wherein the positive electrode active material-containing layer has a filling density of 3.15 g/cm 3 or less.
7. The non-aqueous electrolyte battery according to claim 1 ,
wherein the positive electrode current collector is an aluminum foil subjected to a roughened process.
8. The non-aqueous electrolyte battery according to claim 7 , wherein the roughening process is carried out by polishing by blasting.
9. The non-aqueous electrolyte battery according to claim 1 , wherein the positive electrode active material-containing layer has a filling density of 3.15 g/cm 3 or less.
10. The non-aqueous electrolyte battery according to claim 1 , wherein second carbon particles are superficially coated on, or adhered to, the particles of olivine-type lithium phosphate.
11. The non-aqueous electrolyte battery according to claim 1 , wherein a portion of lithium sites in the positive electrode active material is substituted by a transition metal.
12. The non-aqueous electrolyte battery according to claim 1 , wherein the first carbon particles have BET specific surface area of 70 m 2 /g to 90 m 2 /g.