Process of production and production system of high strength galvannealed steel sheet
View Patent ↗A process of production for producing a high strength galvannealed steel sheet by a hot-dip galvanized steel sheet production equipment using an all radiant tube type annealing furnace and a production equipment for the same are provided, comprising continuously hot-dip galvanizing a high strength steel sheet having a content of Si of 0.4 to 2.0 wt % during which making the atmosphere of the reducing zone an atmosphere containing H 2 to 1 to 60 wt % and comprised of the balance of N 2 , H 2 O, O 2 , CO 2 , CO, and unavoidable impurities, controlling the log (PCO 2 /PH 2 ) of the carbon dioxide partial pressure and hydrogen partial pressure in the atmosphere to log (PCO 2 /PH 2 )≦−0.5 and the log (PH 2 O/PH 2 ) of the water partial pressure and hydrogen partial pressure to log (PH 2 O/PH 2 )≦−0.5, and controlling the log (P T /PH 2 ) of the total partial pressure P T of the carbon dioxide partial pressure PCO 2 and water partial pressure PH 2 O and the hydrogen partial pressure to −3≦log (P T /PH 2 )≦−0.5.
1. A process of production of a high strength galvannealed steel sheet, comprising
pickling a hot-rolled steel sheet having a content of Si of 0.4 to 2.0 wt %,
then, cold-rolling the steel sheet, then, continuously hot-dip galvanizing the steel sheet in an all radiant tube type annealing furnace with a reducing atmosphere and without an oxidizing zone,
wherein the all radiant tube type annealing furnace comprises a heating zone ( 2 ), a soaking zone ( 3 ), a cooling zone ( 4 ), a reducing gas pipe ( 14 ) connecting the heating zone ( 2 ), soaking zone ( 3 ), and cooling zone ( 4 ), and a combustion gas pipe ( 17 ) connecting the heating zone ( 2 ) and soaking zone ( 3 ), and
in the all radiant tube type annealing furnace, a reducing gas ( 15 ) flows into the heating zone ( 2 ), soaking zone ( 3 ), and cooling zone ( 4 ), and a combustion gas ( 18 ) flows into the heating zone ( 2 ) and soaking zone ( 3 ), and
the atmosphere is made not to cause iron to oxidize,
during the continuously hot-dip galvanizing:
introducing the combustion gas ( 18 ) containing CO 2 in an amount of 1 to 100 wt % and a balance of N 2 , H 2 O, O 2 , CO, and unavoidable impurities into the heating zone ( 2 ), and soaking zone ( 3 ) of the annealing furnace,
making the atmosphere of the annealing furnace an atmosphere containing H 2 to 1 to 60 wt % and the balance being N 2 , H 2 O, O 2 , CO 2 , CO, and unavoidable impurities,
controlling, in the atmosphere,
(i) the log(PCO 2 /PH 2 ) of the carbon dioxide partial pressure and hydrogen partial pressure to log(PCO 2 /PH 2 )≦−0.5,
(ii) the log(PH 2 O/PH 2 ) of the water partial pressure and hydrogen partial pressure to log(PH 2 O/PH 2 )≦−0.5, and
(iii) the log(P T /PH 2 ) of (a) the total partial pressure P T of the carbon dioxide partial pressure PCO 2 , the water partial pressure PH 2 O, and the hydrogen partial pressure PH 2 and (b) the hydrogen partial pressure PH 2 to −3≦log(P T /PH 2 )≦−0.5,
performing annealing in the reducing atmosphere in a ferrite-austenite two-phase temperature region at 720° C. to 880° C.,
then cooling by a plating bath and performing molten zinc plating so as to form a hot-dip galvanizing layer on the surface of the steel sheet, and
then heating for alloying the steel sheet on which the hot-dip galvanizing layer is formed at 460 to 550° C., so as to produce a high strength galvannealed steel sheet.
2. A process of production of a high strength galvannealed steel sheet as set forth in claim 1 , characterized by performing the hot-dip galvanizing in a hot-dip galvanizing bath of a composition comprised of an effective Al concentration in the bath of at least 0.07 wt % and the balance being Zn and unavoidable impurities and performing the alloying at a temperature T (° C.) satisfying 450≦T≦410×exp(2×[Al %]), where, [Al %]: effective Al concentration (wt %) in the hot-dip galvanizing bath.
3. A process of production of a high strength galvannealed steel sheet as set forth in claim 1 , the effective Al concentration (wt %) in the bath satisfying [Al %]≦0.092−0.001×[Si %] 2 , where, [Si %]: Si content in steel sheet (wt %).