Laser sintering processes using thermoplastic compositions
View Patent ↗A method of laser sintering a thermoplastic composition to provide an article of manufacture having a plurality of sintered layers is disclosed. The thermoplastic composition has a relatively high melting point and a small particle size. The articles of manufacture have a high resolution and excellent durability and strength.
1. A method of manufacturing an article comprising laser sintering a thermoplastic composition comprising a thermoplastic block copolymer having a melting point of about 180° C. to 195° C.
2. The method of claim 1 wherein the thermoplastic composition comprises at least 90%, by weight, of the thermoplastic copolymer.
3. The method of claim 1 wherein the thermoplastic composition comprises at least 95%, by weight, of the thermoplastic copolymer.
4. The method of claim 1 wherein the block copolymer comprises soft and hard segments.
5. The method of claim 4 wherein the soft segment comprises an ether or an ester.
6. The method of claim 4 wherein the hard segment comprises an ester, amide, or urethane.
7. The method of claim 1 wherein the block copolymer has a melting point of about 185° C. to 195° C.
8. The method of claim 1 wherein the block copolymer has a melting point of about 190° C. to 195° C.
9. The method of claim 1 wherein the block copolymer has a d90 of about 90 to about 100 μm.
10. The method of claim 9 wherein the block copolymer has a median particle size of about 40 to about 60 μm.
11. The method of claim 10 wherein the block copolymer has a particle size range of about 1 to about 150 μm.
12. The method of claim 1 wherein the block copolymer has a heat of fusion of about 15 to about 35 Joules/gram.
13. The method of claim 1 wherein the block copolymer comprises a polyether-ester elastomer.
14. The method of claim 13 wherein the polyether elastomer comprises polybutylene phthalate segments and long-chain polyalkylenether glycol segments.
15. The method of claim 1 wherein thermoplastic composition further comprises a flow agent in an amount of about 0.05% to about 5%, by weight, of the composition.
16. The method of claim 15 wherein the flow agent has a median particle size of about 10 microns or less.
17. The method of claim 15 wherein the flow agent is selected from the group consisting of hydrated silica, amorphous alumina, a glassy silica, a glassy phosphate, a glassy borate, a glassy oxide, titania, talc, mica, a fumed silica, kaolin, attapulgite, calcium silicate, alumina, magnesium silicate, and mixtures thereof.
18. The method of claim 15 wherein the flow agent comprises a fumed silica.
19. The method of claim 1 wherein the thermoplastic composition comprises about 0.1% to about 30%, by weight, in total, of an optional ingredient selected from the group consisting of a coloring agent, a filler, a second modifying polymer, and mixtures thereof.
20. The method of claim 19 wherein the coloring agent comprises carbon black.
21. The method of claim 19 wherein the second modifying polymer comprises a polyamide.
22. The method of claim 21 wherein the polyamide is selected from the group consisting of nylon 6, nylon 66, nylon 11, nylon 610, nylon 12, nylon 612, a copolymerized nylon, and mixtures thereof.
23. The method of claim 15 wherein the thermoplastic block copolymer comprises a polyether-ester elastomer and the flow agent comprises a fumed silica.
24. The method of claim 23 wherein the thermoplastic composition further comprises about 0.1% to about 30%, by weight, of a polyamide.
25. A method of manufacturing an article comprising the steps of
(a) depositing a quantity of a thermoplastic composition on a support surface;
(b) leveling the composition to form a smooth layer of the composition on the support surface;
(c) then directing an energy beam over a predetermined target area on the support surface causing the composition to form an integral layer; and
(d) repeating steps (a) to (c) to form additional layers that are integrally bonded to adjacent layers to form a three-dimensional article,
wherein the thermoplastic composition comprises a thermoplastic composition comprising a thermoplastic block copolymer having a melting point of about 180° C. to 195° C.
26. The method of claim 25 wherein the article is free of an infiltration step performed after step (d).