Lithium ion secondary battery and method for manufacturing same
View Patent ↗A lithium ion secondary battery with improved safety against both internal short-circuiting and overcharge is provided. This lithium ion secondary battery includes a positive electrode comprising a composite lithium oxide, a negative electrode, and a non-aqueous electrolyte. At least one of the positive electrode and the negative electrode has a porous film, comprising an inorganic oxide filler and a binder, on the surface facing the other electrode, and the electrode surface having the porous film partially has a protruded part. This protruded part may be a protruded part formed on the porous film itself or a protruded part formed on an electrode mixture layer. Further, a separator can also be incorporated therein. Instead of the above-mentioned porous film, the separator can be provided with a porous film.
1. A lithium ion secondary battery comprising:
a positive electrode comprising a composite lithium oxide;
a negative electrode; and
a non-aqueous electrolyte,
wherein at least one of said positive electrode and said negative electrode has a porous film, comprising an inorganic oxide filler and a binder, on the surface facing the other electrode, and said electrode surface having the porous film partially has a protruded part, the ratio of the electrode surface having the protruded part being between 1/10 and 1.5/9.5.
2. The lithium ion secondary battery in accordance with claim 1 , further comprising a separator between said positive electrode and said negative electrode.
3. The lithium ion secondary battery in accordance with claim 1 , wherein said protruded part comprises a protruded part that is partially formed on the surface of said porous film.
4. The lithium ion secondary battery in accordance with claim 1 wherein said electrode having the porous film has an electrode mixture layer that partially has a protruded part.
5. A method for producing the lithium ion secondary battery of claim 3 , comprising the steps of: applying a slurry for forming the porous film onto a surface of an electrode mixture layer that comprises an electrode active material, a conductive agent and a binder and drying the slurry to form the porous film; and
applying the slurry for forming the porous film onto said porous film in a predetermined pattern and drying the slurry to form the protruded part.
6. A method for producing the lithium ion secondary battery of claim 3 , comprising the step of applying a slurry for forming the porous film onto a surface of an electrode mixture layer that comprises an electrode active material, a conductive agent and a binder by a die coater process while partially increasing the amount of the slurry applied, to form the porous film partially having the protruded part.
7. A method for producing the lithium ion secondary battery of claim 4 , comprising the steps of:
inscribing the protruded part on a surface of an electrode mixture layer comprising an electrode active material, a conductive agent and a binder; and
applying a slurry for forming the porous film onto the surface of the electrode mixture layer inscribed with said protruded part and drying the slurry to form the porous film.