Method to make single-layer PET bottles with high barrier and improved clarity
View Patent ↗The present invention comprises a blend of polyester and a partially aromatic polyamide with an ionic compatibilizer and a cobalt salt. This blend can be processed into a container that has both active and passive oxygen barrier and carbon dioxide barrier properties at an improved color and clarity than containers known in the art. The partially aromatic polyamide is preferably meta-xylylene adipamide. The ionic compatibilizer is preferably 5-sodiumsulfoisophthalic acid or 5-zincsulfoisophthalic acid, or their dialkyl esters such as the dimethyl ester (SIM) and glycol ester (SIPEG). The cobalt salt is selected form the class of cobalt acetate, cobalt carbonate, cobalt chloride, cobalt hydroxide, cobalt naphthenate, cobalt oleate, cobalt linoleate, cobalt octoate, cobalt stearate, cobalt nitrate, cobalt phosphate, cobalt sulfate, cobalt (ethylene glycolate), or mixtures of two or more of these. The partially aromatic polyamide is present in a range from about 1 to about 10 wt. % of said composition. The ionic compatibilizer is present in a range from about 0.1 to about 2.0 mol-% of said composition. The cobalt salt is present in a range from about 20 to about 500 ppm of said composition.
1. A composition for containers comprising: polyester, partially aromatic polyamide, ionic compatibilizer, and a cobalt salt; wherein said ionic compatibilizer is a copolyester containing a metal sulfonate salt.
2. The composition of claim 1 , wherein said partially aromatic polyamide is present in a range from about 1 to about 10 wt. % of said composition.
3. The composition of claim 1 , wherein said ionic compatibilizer is present in a range from about 0.1 to about 2.0 mole % of said composition.
4. The composition of claim 1 , wherein said cobalt salt is present in a range from about 20 to about 500 ppm of said composition.
5. The composition of claim 1 , wherein said partially aromatic polyamide contains meta-xylylene.
6. The composition of claim 5 , wherein said partially aromatic polyamide is poly(meta-xylylene adipamide).
7. The composition of claim 1 , wherein said partially aromatic polyamide is selected from the group consisting of poly(hexamethylene isophthalamide), poly(hexamethylene adipamide-co-isophthalamide), poly(hexamethylene adipamide-co-terephthalamide), poly(hexamethylene isophthalamide-co-terephthalamide), and mixtures of two or more of these.
8. The composition of claim 1 , wherein said cobalt salt is selected from the group consisting of cobalt acetate, cobalt carbonate, cobalt chloride, cobalt hydroxide, cobalt naphthenate, cobalt oleate, cobalt linoleate, cobalt octoate, cobalt stearate, cobalt nitrate, cobalt phosphate, cobalt sulfate, cobalt (ethylene glycolate), and mixtures of two or more of these.
9. The composition of claim 1 , wherein the metal ion of the metal sulfonate salt is selected from the group consisting of Na+, Li+, K+, Zn++, Mn++, and Ca++.
10. The composition of claim 9 , wherein said metal sulfonate salt is attached to an aromatic acid nucleus selected from the group consisting of sulfophthalic acid, sulfoterephthalic acid, sulfoisophthalic acid, 4-sulfonaphthalene-2,7-dicarboxylic acid, and esters of each.
11. The composition of claim 1 , wherein said metal sulfonate salt is 5-sodiumsulfoisophthalic acid, 5-zincsulfoisophthalic acid, or dialkyl esters thereof.
12. The composition of claim 11 wherein the dialkyl ester is a dimethyl ester (SIM) or a glycol ester (SIPEG).
13. An article comprising a composition comprising polyester, partially aromatic polyamide, ionic compatibilizer, and a cobalt salt;
wherein said ionic compatibilizer is a copolyester containing a metal sulfonate salt and wherein said article is a preform or a container.
14. The article of claim 13 , wherein said partially aromatic polyamide is present in a range from about 1 to about 10 wt. % of said composition.
15. The article of claim 13 , wherein said ionic compatibilizer is present in a range from about 0.1 to about 2.0 mole % of said composition.
16. The article of claim 13 , wherein said cobalt salt is present in a range from about 20 to about 500 ppm of said composition.
17. The article of claim 13 , wherein said partially aromatic polyamide contains meta-xylylene.
18. The article of claim 17 , wherein said partially aromatic polyamide is poly(meta-xylylene adipamide).
19. The article of claim 13 , wherein said partially aromatic polyamide is selected from the group consisting of poly(hexamethylene isophthalamide), poly(hexamethylene adipamide-co-isophthalamide), poly(hexamethylene adipamide-co-terephthalamide), poly(hexamethylene isophthalamide-co-terephthalamide), and mixtures of two or more of these.
20. The article of claim 13 , wherein said cobalt salt is selected from the group consisting of cobalt acetate, cobalt carbonate, cobalt chloride, cobalt hydroxide, cobalt naphthenate, cobalt oleate, cobalt linoleate, cobalt octoate, cobalt stearate, cobalt nitrate, cobalt phosphate, cobalt sulfate, cobalt (ethylene glycolate), and mixtures of two or more of these.
21. The article of claim 13 , wherein the metal ion of the metal sulfonate salt is selected from the group consisting of Na+, Li+, K+, Zn++, Mn++, and Ca++.
22. The article of claim 21 , wherein said metal sulfonate salt is attached to an aromatic acid nucleus selected from the group consisting sulfophthalic acid, sulfoterephthalic acid, sulfoisophthalic acid, 4-sulfonaphthalene-2,7-dicarboxylic acid, and esters thereof.
23. The article of claim 13 , wherein said metal sulfonate salt is 5-sodiumsulfoisophthalic acid, 5-zincsulfoisophthalic acid, or dialkyl esters thereof.
24. The article of claim 23 wherein the dialkyl ester is a dimethyl ester (SIM) or a glycol ester (SIPEG).
25. A polyester container having an oxygen permeation rate of <0.01 cc(STP)-cm/m 2 -atm-day after 100 hours in oxygen, wherein said container comprises a composition of polyester, partially aromatic polyamide, ionic compatibilizer, and a cobalt salt; wherein said ionic compatibilizer is a copolyester containing a metal sulfonate salt.
26. The container of claim 25 , having a yellowness value (b*) of less than 2.5.
27. A polyester container that has a carbon dioxide transmission rate of less than 7 cc/bottle/day, based on a 0.59 liter bottle, wherein said container comprises a composition of polyester, partially aromatic polyamide, ionic compatibilizer, and a cobalt salt; wherein said ionic compatibilizer is a copolyester containing a metal sulfonate salt.