Polypropylene based resin composition, expanded moldings comprising the same and method for production thereof
View Patent ↗A polypropylene-based resin composition for injection foam molding, containing (A) 50 to 95 parts by weight of a linear polypropylene-based resin having a melt flow rate of from 10 g/10 min. to 100 g/10 min. and a melt tension of 2 cN or less and (B) 5 to 50 parts by weight of a modified polypropylene having a melt flow rate of from 0.1 g/10 min. to less than 10 g/10 min. and a melt tension of 5 cN or more and exhibiting a strain hardening property (provided that a total of the resin (A) and the resin (B) is 100 parts by weight) and a foaming agent are supplied to an injection molding machine to be injected into a die, thereby achieving a foam molding. It is thus possible to obtain a injection foamed molded article which has a satisfactory injection foam moldability, a skin layer having little silver streaks or the like on its surface, and an internal core layer having a foam of high expansion ratio and uniformly fine and a excellent appearance glossiness, lightweightness, and rigidity at a low cost.
1. A process for preparing a polypropylene-based resin foamed molded article comprising supplying a polypropylene-based resin composition for injection foam molding and a foaming agent to an injection molding machine and forming a melt mixture and injecting said melt mixture into a die for foam molding, wherein said foam-molding is performed by injecting said melt mixture into a die which is pressurized with a gaseous substance to a pressure preventing foaming at a flow front of the melt mixture and said polypropylene-based resin composition for injection foam molding comprises:
(A) 50 to 95 parts by weight of a linear polypropylene-based resin having a melt flow rate of from 10 g/10 min. to 100 g/10 min. and a melt tension of not more than 2 cN;
(B) 5 to 50 parts by weight of a modified polypropylene having a melt flow rate of from 0.1 g/10 mm. to less than 10 g/10 min. and a melt tension of 5 cN or more and exhibiting a strain hardening property (provided that a total of the linear polypropylene-based resin (A) and the modified polypropylene-based resin (B) is 100 parts by weight).
2. The process for preparing a polypropylene-based resin foamed molded article according to claim 1 , wherein the modified polypropylene-based resin (B) is obtained by melt-mixing a linear polypropylene-based resin, a radical polymerization initiator, and a conjugated diene compound.
3. A foamed molded article made by the process of claim 1 or 2 .
4. The foamed molded article according to claim 3 , comprising:
a foamed layer having an average cell diameter of not more than 500 μm, and a non-foamed layer formed on a surface of at least one side of the foamed layer and having a thickness of from 10 μm to 1,000 μm; and
said foamed molded article having an expansion ratio of from 2 to 10, and a thickness of not more than 30 mm.
5. A process for preparing the foamed molded article according to claim 1 , wherein said die for foam molding comprises a fixed die and a movable die capable of advancing and retrieving to arbitrary positions and foaming with the movable die being retrieved after the injection.
6. The process for preparing a polypropylene-based resin foamed molded article according to claim 1 , wherein the pressure for pressurizing the die in advance of the injection of the melt mixture is from 0.1 MPa to 5 MPa.