Polypropylene composition for air quenched blown films
View Patent ↗The invention is directed to a polypropylene resin, which is suitable for manufacturing an air quenched blown film. The resin has a melt flow rate of greater than 5 g/10 min, less than 2% xylene solubles, a pentad isotacticity of greater than 95%, an isotactic pentad/triad ratio of greater than 95%, a crystallinity of at least 65%, and a crystallization temperature of at least 127° C. The polypropylene resin contains from 500 ppm to 2500 ppm of a nucleator/clarifier additive. A quenched blown film made from resin exhibits a crystallization onset temperature of at least 116° C. and a crystallization half-life time of less 4.1 seconds or less when tested using fast DSC analysis with a scan rate of 200° C./minute.
1. A polypropylene, suitable for forming a blown film, the polypropylene comprising: a polypropylene copolymer containing less than 2% by weight units derived from ethylene and having a M w /M n of less than 6.0, a melt flow rate of from 7 to 20 g/10 min g/10 min, less than 3% xylene solubles, a pentad isotacticity of greater than 91%, an isotactic pentad/triad ratio of greater than 95%, a crystallinity of at least 65%, and a crystallization temperature of at least 127° C., the polypropylene containing from 750 ppm to 2500 ppm of a nucleator/clarifier additive, wherein said additive is methylene-bis(4,6-di-tert-butylphenyl) phosphate sodium salt, and wherein a blown film is capable of being manufactured from the polypropylene at a rate of at least 6 lb/hr-in of die circumference and wherein a one mil thick blown film manufactured from the polypropylene using at least a 1.5 blow-up ratio exhibits a 1% secant modulus of at least 150,000 psi according to ASTM D882, a haze of less than 10 as measured by ASTM D1003, and a clarity of greater than 96%.
2. The polypropylene of claim 1 , wherein the polypropylene copolymer has a Mw/Mn of less than 5.5, less than 2% xylene solubles, a pentad isotacticity of greater than 95%, a isotactic pentad/triad ratio of greater than 98%, a crystallinity of at least 67%, and a crystallization temperature of at least 128° C.
3. The polypropylene of claim 2 , wherein polypropylene copolymer contains from 0.1 to 0.7% by weight units derived from ethylene and wherein a one mil thick blown film manufactured from the polypropylene exhibits a 1% secant modulus of at least 165,000 psi according to ASTM D882.
4. The polypropylene of claim 2 , wherein a one mil thick blown film manufactured from the polypropylene exhibits a 1% secant modulus of at least 180,000 psi according to ASTM D882.
5. The polypropylene of claim 2 , wherein a one mil thick blown film manufactured from the polypropylene exhibits a 1% secant modulus of at least 200,000 psi according to ASTM D882.
6. The polypropylene of claim 1 , wherein the one mil thick film manufactured from the polypropylene lies flat on the take up roll with no significant wrinkles and has a gauge variation of less than 10%.
7. An air quenched blown film made from the polypropylene of claim 1 .
8. The film of claim 7 , wherein the film comprises a monolayer film.
9. The film of claim 7 , wherein the film comprises a multi layer, coextruded, blown film, the film being comprised of at least a first and a second layer, said polypropylene being contained in the first layer.
10. The film of claim 9 , wherein the second layer comprises a thermoplastic.
11. The film of claim 9 , wherein the second layer comprises an ethylene-based polymer having a majority of monomer units derived from ethylene.
12. The film of claim 7 , wherein the film is manufactured at a rate of at least 6 lb/hr-inch die circumference using a blow-up ratio of at least 1.5.
13. The film of claim 7 , wherein the film is manufactured at a rate of at least 8 lb/hr-inch die circumference using a blow-up ratio of at least 1.5.
14. The film of claim 12 or 13 , wherein the film is manufactured using a blow-up ratio of at least 2.5.
15. The film of claim 10 , wherein the second layer is comprised of polymers selected from the group consisting of: EVOH, PVDC, polyvinylidene chloride, EVA, EAA, maleic anhydride grafted polypropylene or polyethylene, EMA, ethylene-acrylate copolymers, acrylic acid copolymers, and mixtures thereof.