IP Library Granted Patent US 7,632,555
Granted Patent B2
US 7,632,555 · App. 10/583,528 · Granted Dec 15, 2009

Inkjet recording element

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Quick Facts
Patent No.
US 7,632,555
App. No.
10/583,528
Granted
Dec 15, 2009
Kind
B2
Abstract

The present invention relates to a recording element intended for forming images by inkjet printing having very good colorfastness over time and a good ink drying time. Said recording element comprises a support and at least one ink-receiving layer, said ink-receiving layer comprising at least one hydrosoluble binder and at least one aluminosilicate polymer capable of being obtained according to a preparation method consisting in treating an aluminum halide with an alkyl orthosilicate only having hydrolyzable functions with an aqueous alkali in the presence of silanol groups, the aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3; and then stirring the resulting mixture at ambient temperature in the presence of silanol groups for long enough to form the aluminosilicate polymer; and then adding at least one aluminum chelating agent to the aluminosilicate polymer, the molar ratio between the chelating functions of the chelating agent and the aluminum of the aluminosilicate polymer being greater than or equal to 1.

Claims (21)

1. An inkjet recording element comprising a support and at least one ink-receiving layer, characterized in that said ink-receiving layer comprises at least one hydrosoluble binder and at least one aluminosilicate polymer obtainable by a preparation method that comprises the following steps:

a) treating a mixed aluminum and silicon alkoxide only comprising hydrolyzable functions, or a mixed aluminum and silicon precursor resulting from the hydrolysis of a mixture of aluminum compounds and silicon compounds only comprising hydrolyzable functions, with an aqueous alkali, in the presence of silanol groups, the aluminum concentration being maintained at less than 0.3 mol/l, the Al/Si molar ratio being maintained between 1 and 3.6 and the alkali/Al molar ratio being maintained between 2.3 and 3;

b) stirring the mixture resulting from step a) at ambient temperature of between 15° C. and 35° C. in the presence of silanol groups long enough to form the aluminosilicate polymer, and, directly after step (b);

c) eliminating the byproducts formed during steps a) and b) from the reaction medium; and

d) adding at least one chelating agent of aluminum to the aluminosilicate polymer, the molar ratio between the chelating functions of the chelating agent and the aluminum of the aluminosilicate polymer being greater than or equal to 1.

2. The recording element according to claim 1 , wherein the alkali of step a) to prepare the aluminosilicate polymer is selected from the group consisting of sodium, potassium, or lithium hydroxide, diethylamine and triethylamine.

3. The recording element according to claim 1 , wherein the silanol groups used to prepare the aluminosilicate polymer are supplied as silica or glass beads.

4. The recording element according to claim 1 , wherein the aluminum concentration used to prepare the aluminosilicate polymer is maintained between 1.5×10 −2 and 0.3 mol/l.

5. The recording element according to claim 1 , wherein the aluminum concentration used to prepare the aluminosilicate polymer is maintained between 4.4×10 −2 and 0.3 mol/l.

6. The recording element according to claim 1 , wherein said alkali/Al molar ratio to prepare the aluminosilicate polymer is about 2.3.

7. The recording element according to claim 1 , wherein said alkali/Al molar ratio to prepare the aluminosilicate polymer is about 3.

8. The recording element according to claim 1 , wherein the method for preparing the aluminosilicate polymer comprises, after step b) and before step c), a step e), by which alkali is added in order to reach an alkali/Al molar ratio of 3 if this ratio has not already been reached in step a).

9. The recording element according to claim 1 , wherein the mixed aluminum and silicon precursor resulting from hydrolysis of a mixture of aluminum compounds and silicon compounds only having hydrolyzable functions is a product resulting from the mixture in an aqueous medium (i) of a compound selected from the group consisting of aluminum salts, aluminum alkoxides and aluminum halogenoalkoxides and (ii) at least one compound selected from the group consisting of silicon alkoxides and chloroalkoxides only having hydrolyzable functions.

10. The recording element according to claim 9 , wherein said mixed aluminum and silicon precursor is the product resulting from the mixture (i) of an aluminum halide and (ii) a silicon alkoxide only having hydrolyzable functions.

11. The recording element according to claim 10 , wherein said silicon alkoxide only having hydrolyzable functions is tetramethyl orthosilicate or tetraethyl orthosilicate.

12. The recording element according to claim 1 , wherein step d) is directly applied to the aluminosilicate polymer resulting from step b) or from step c) or at the time of the preparation of the coating composition for the ink-receiving layer from an aluminosilicate polymer resulting from step c).

13. The recording element according to claim 1 , wherein the chelating agent of aluminum is selected from the group consisting of carboxylic acids, phosphonic acids, phosphinic acids, sulfonic acids, difunctional acids, their esters and anhydrides, and amino acids.

14. The recording element according to claim 13 , wherein said chelating agent of aluminum is selected from the group consisting of HCOOH, R 1 COOH, where R 1 is selected from the group consisting of CH 3 (CH 2 ) n , n being between 0 and 12, CF 3 , C 6 H 5 , (C 6 H 5 ) 2 , substituted aromatic rings, C 4 H 4 S; R 2 PO(OH) 2 where R 2 is selected from the group consisting of CH 3 , C 6 H 5 ; R 3 SO 3 H where R 3 is CH 3 (CH 2 ) n , n being between 0 and 5; HOOC(CH 2 )COOH, n=0-8; aromatic difunctional acids; HOOC(CH 2 ) n PO(OH) 2 , n=2, 4; aliphatic hydroxy acids; HOOC(CH 2 OH) n COOH, n=1-2; CH 3 CH(NH 2 )COOH.

15. The recording element according to claim 1 , wherein step d) comprises a first adding of acetic acid and a following adding of another chelating agent of aluminum.

16. The recording element according to claim 1 , wherein said ink-receiving layer comprises between 5 and 95 percent by weight of aluminosilicate polymer compared with the total weight of the dry ink-receiving layer.

17. The recording element according to claim 1 , wherein the hydrophilic binder is gelatin or polyvinyl alcohol.

Assignments (9)
RELEASE OF SECURITY INTEREST Recorded Jan 24, 2020
From: BARCLAYS BANK PLC
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST) INC.; KODAK AMERICAS LTD.; KODAK REALTY INC.; LASER PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES LTD.; NPEC INC.
Reel/Frame 052773/0001 →
RELEASE OF SECURITY INTEREST Recorded Jul 22, 2019
From: JP MORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC, INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX, INC.; KODAK PHILIPPINES, LTD.; NPEC, INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
Reel/Frame 049814/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (FIRST LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC; KODAK AMERICAS, LTD.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE
Reel/Frame 031158/0001 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Sep 5, 2013
From: CITICORP NORTH AMERICA, INC., AS SENIOR DIP AGENT; WILMINGTON TRUST, NATIONAL ASSOCIATION, AS JUNIOR DIP AGENT
To: EASTMAN KODAK COMPANY; PAKON, INC.
Reel/Frame 031157/0451 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (SECOND LIEN) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BARCLAYS BANK PLC, AS ADMINISTRATIVE AGENT
Reel/Frame 031159/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Sep 5, 2013
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; KODAK IMAGING NETWORK, INC.; KODAK PORTUGUESA LIMITED; KODAK REALTY, INC.; LASER-PACIFIC MEDIA CORPORATION; PAKON, INC.; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.; CREO MANUFACTURING AMERICA LLC; KODAK AVIATION LEASING LLC
To: BANK OF AMERICA N.A., AS AGENT
Reel/Frame 031162/0117 →
PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 030122/0235 →
SECURITY INTEREST Recorded Feb 21, 2012
From: EASTMAN KODAK COMPANY; PAKON, INC.
To: CITICORP NORTH AMERICA, INC., AS AGENT
Reel/Frame 028201/0420 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 16, 2006
From: DESROUSSEAUX, STEPHANIE V.; PONCELET, OLIVIER J.
To: EASTMAN KODAK COMPANY
Reel/Frame 018049/0366 →