Aromatic polyester composition for making stretch blow molded containers
View Patent ↗The present invention relates to an aromatic polyester composition for making stretch blow molded containers with improved strain hardening. The polyester composition according to the invention exhibits a low DEG content, a natural stretch ratio of <10, a half time of crystallization of >150 sec at 200° C. and comprises a sulfo-modified copolymer. Compared to polyesters of the prior art, the polyester of the present invention exhibits superior stretching characteristics, such as a lower natural stretch ratio (NSR), which allows for production of small PET bottles via thinner and longer parisons. Such thinner and longer parisons improve the production of small containers due to shorter cooling cycles.
1. Polyester resin comprising at least 85 Mol-% of polyethylene terephthalate and at least 0.01 Mol-%, but not more than 5.00 Mol-% of units of the formula (I)
wherein
wherein n is an integer from 3 to 10 and
wherein M + is an alkali metal ion, earth alkali metal ion, phosphonium ion or ammonium ion and wherein the polyester contains <5.0 wt.-% of diethylene glycol and wherein the polyester contains Na 2 HPO 4 in an amount such that the phosphor content is 10 to 200 ppm (based on the weight of the polyester) and wherein the polyester is either free of or does not contain more than 9 ppm of NaH 2 PO 4, and wherein the intrinsic viscosity is 0.6 to 1.0.
2. Polyester resin according to claim 1 , wherein
3. Polyester resin according to claim 1 , wherein
4. Polyester resin according to claim 2 , wherein the attachments to the phenyl ring are in 1-, 3- and 5-position and the attachment to the naphthyl ring are in 2-, 4- and 6-position.
5. Polyester resin according to claim 1 , wherein M + is Li + , Na + or K + .
6. Polyester resin according to claim 1 , wherein the Na 2 HPO 4 (disodium monohydrogenphosphate) is in the form of the dodeca-hydrate (.12 H 2 O).
7. Polyester resin according to claim 1 , further comprising <10 Mol-% of modifying agents.
8. Polyester resin according to claim 1 , wherein the NSR is <10.
9. Polyester resin according to claim 1 , wherein the half time of crystallization is <150 sec at 200° C.
10. Method of manufacturing a polyester resin according to claim 1 , comprising the steps of
a) reacting terephthalic acid (TA) or C 1 -C 4 -dialkyl terephthalate; and ethylene glycol (EG); and at least 0.01, but not more than 5.00 Mol-% of a compound according to formula (II):
wherein R is hydrogen, a C 1 -C 4 -alkyl or a C 1 -C 4 -hydroxyalkyl and M and
have the meaning given in claim I for formula (I) and
b) subjecting the reaction product of a) to a polycondensation reaction to form the polymer.
11. The method according to claim 10 , wherein
12. The method according to claim 10 , wherein
13. The method according to claim 11 , wherein the attachments to the phenyl ring are in 1-, 3- and 5-position and the attachment to the naphthyl ring are in 2-, 4- and 6-position.
14. The method according to claim 11 , wherein the polyester contains Na 2 HPO 4 in an amount such that the phosphor content is 10 to 200 ppm (based on the weight of the polyester).
15. The method according to claim 11 , wherein the polyester contains <2.5 wt.-% of diethylene glycol.
16. The method according to claim 11 , wherein the polyester contains Na 2 HPO 4 in an amount such that the phosphor content is 10 to 200 ppm (based on the weight of the polyester) and wherein the polyester contains <2.5 wt.-% of diethylene glycol.
17. Polyester resin according to claim 1 , wherein the polyester contains Na 2 HPO 4 in an amount such that the phosphor content is 10 to 200 ppm (based on the weight of the polyester).
18. Polyester resin according to claim 1 , wherein the polyester contains <2.5 wt-% of diethylene glycol.
19. Polyester resin according to claim 1 , wherein the polyester contains Na 2 HPO 4 in an amount such that the phosphor content is 10 to 200 ppm (based on the weight of the polyester) and wherein the polyester contains <2.5 wt.-% of diethylene glycol.